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The effects of engine and after-treatment control conditions on emissions fluctuation were evaluated and the technical idea for improving the repeatability in tailpipe emission measurement from DISI vehicles was provided. To improve measurement repeatability, low emissions analyzers with dilution air refining system were employed for this research. In addition, a new device that enabled monitoring of signals from the Engine Control Unit (ECU) was developed. A novel approach using these devices was applied to DISI gasoline engine vehicles equipped with de-NOx catalyst to clarify emission characteristics in the Japanese 10.15 test cycle emission tests. Through the tests, it is found that NOx emissions most correlated with the temperature at the de-NOx catalyst. CO and HC reaching the de-NOx catalyst played an important role in the temperature increase of de-NOx catalyst by exothermic reactions.

The accuracy and precision of exhaust gas mass emission measurement has recently come under close scrutiny as the absolute mass emission level has become lower. The uncertainty of the mass emission measurement can not be defined simply as it is a combination of many parameters in the measurement system. This paper lists and reviews the major factors that affect the accuracy in super-low emission measurement when using a constant volume sampler (CVS), such as analyzer performance, HC contamination, excessive dilution of sample gases, error in DF calculations and the variation of vehicle emission itself. Additionally, an alternative sampling system, using the bag mini-diluter (BMD) technique, is investigated in comparison with the enhanced CVS system, i.e. use of dilution air refiner, and heating of the whole system. Some ideas for reducing the HC contamination are also described as it is an important parameter that affects measurement accuracy in both the CVS and BMD systems.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

Investigation of operating parameters have been carried out for an FTIR system dedicated for emission analysis. Discussions are focused on the key parameters, such as spectral resolution, gas cell dimensions, quantification algorithm, and sample gas treatment. The spectral resolution has to be determined so that the scan rate is high enough to make transient analysis, the minimum detection limit is low enough to carry out high sensitivity measurement, and no cross sensitivity can be recognized. A trade-off relationship between the response and the sensitivity exists for the gas cell design. Small volume of the cell is desirable when gas replacement is considered. On the other hand, the sensitivity can be increased by enlarging the cell volume to obtain long optical path. Both quantification algorithm and the sample gas treatment have to be well arranged to obtain accurate concentration values of the gas compounds sampled from the tailpipe.

Two new techniques have been applied to FTIR emission analysis which add significant potential to automotive emission measurement. One of these is the use of the mathematical multivariate analysis which is called the partial least squares method. This spectrum discrimination technique, in combination with high resolution spectrum data, enables superior analysis for heavy-overlapping species in the emission. The other technique is a flow conditioned gas sampling cell which is designed especially for real time emission measurement. The flow in the gas cell has been analyzed with computer simulation and the gas cell has a flow conditioner inside with a 10 meter optical path. Seven seconds of 90 percent gas replacement time can be achieved with this cell. As a result, highly accurate realtime data can be obtained with relatively fast response. In this paper, spectrum factors extracted from overlapping species and quantification simulations are shown using standard gases.