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Thermal barrier coatings have been shown to be effective at reducing particulate emissions from diesel engines. Prior work by the authors has demonstrated a significant decrease in particulate emissions from a thermal barrier coated, single-cylinder, indirect injection (IDI) diesel engine, primarily through reduction of the volatile (VOF) and soluble (SOF) fraction of the particulate. Most of this prior work relied on conventional, commercially available, petroleum-based lubricants. Recently, the authors demonstrated additional particulate emissions reductions when a high oleic sunflower-based lubricant was used instead of a conventional petroleum-based lubricant. This paper concerns the manner in which the particulate was reduced, and reports on the changes in particulate composition and morphology between the two lubricants. Composition was examined quantitatively through thermal analysis of the particulate from a single-cylinder IDI diesel engine.

Thermal barrier coated diesel engines, also known as low heat rejection (LHR) engines, have offered the promise of reducing heat rejection to the engine coolant and thereby increasing overall thermal efficiency. However, the larger market potential for thermal barrier coated engines may be in retrofitting in-service diesel engines to reduce particulate emissions. Prior work by the authors has demonstrated a significant decrease in particulate emissions from a thermal barrier coated, single-cylinder, indirect injection (IDI) diesel engine, primarily through reduction of the volatile (VOF) and soluble (SOF) fraction of the particulate. This prior work relied on conventional, commercially available, petroleum-based lubricants. The present study concerns the additional benefits for particulate reduction provided by vegetable oil lubricants. These lubricants are derived from renewable resource materials and can provide a reduction in lubricant generated particulate matter.