Search Results

The development of new catalytic materials is still dominated by trial and error methods, even though the experimental and theoretical bases for their characterization have improved dramatically in recent years. Although it has been successful, the empirical development of catalytic materials is time consuming and expensive with no guarantee of success. We have been exploring computationally complex but experimentally simple systems to establish a “catalysis by design” protocol that combines the power of theory and experiment. We hope to translate the fundamental insights directly into a complete catalyst system that is technologically relevant. The essential component of this approach is that the catalysts are iteratively examined by both theoretical and experimental methods.

A low-pressure CO2-based climate-control system has the environmental benefits of CO2 refrigerant but avoids the extremely high pressures of the transcritical CO2 cycle. In the new cycle, a liquid “cofluid” is circulated in tandem with the CO2, with absorption and desorption of CO2 from solution replacing condensation/gas cooling and evaporation of pure CO2. This work compares the theoretical performance of the cycle using two candidate cofluids: N-methyl-2-pyrrolidone and acetone. The optimal coefficient of performance (COP) and refrigeration capacity are discussed in terms of characteristics of the CO2-cofluid mixture. Thermodynamic functions are determined either from an activity coefficient model or using the Soave equation of state, with close agreement between the two approaches. Reductions in COP due to nonideal compressor and heat exchangers are also estimated.

Carbon dioxide (CO2)-based refrigeration systems have been proposed as environmentally benign alternatives to current automotive air conditioners. The CO2 vapor-compression system requires very high operating pressures and complicated control strategies. Recent experimental results indicate that operating pressures comparable to those of current automotive air conditioners can be attained by the inclusion of a secondary carrier fluid (a “co-fluid”), with solution and desolution of the CO2 from the co-fluid substituting for condensation and vaporization of pure CO2. In this work, modeling tools have been developed to optimize the CO2/co-fluid cycle, including the selection of a co-fluid, the CO2/co-fluid ratio (the “loading”), and the operating conditions.

The environmental impact of manufacturing operations is a continuing concern due to increasing regulatory pressures, heightening public awareness about the environment, and rising costs associated with the treatment and disposal of wastes. Ford Motor Company has adopted a proactive waste minimization strategy for handling manufacturing emissions in a cost-effective fashion. A waste opportunity assessment was performed at the Livonia Transmission Plant and succeeded in identifying over $1.2 million in waste reduction opportunities. The assessment suggests that immediate, low-cost opportunities to reduce waste generation exist at Ford facilities. These short-term opportunities can be addressed without major process or facility modifications, but they do require a greater investment in time and resources to identify problem areas and to act on them.