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This paper offers a concept for a regenerable, low-power system for purifying exhaust from a solid waste processor. The innovations in the concept include the use of a closed-loop regeneration cycle for the adsorber, which prevents contaminants from reaching the breathable air before they are destroyed, and the use of a humidity-swing desorption cycle, which uses less power than a thermal desorption cycle and requires no venting of air and water to space vacuum or planetary atmosphere. The process would also serve well as a trace contaminant control system for the air in the closed environment. A systems-level design is presented that shows how both the exhaust and air purification tasks could be performed by one processor. Data measured with a fixed-bed apparatus demonstrate the effects of the humidity swing on regeneration of the adsorbent.

Effects of a cabin-level humidity upset on an activated carbon column used for adsorption of trace compounds from air are examined through a series of experiments and computer simulations. Breakthrough curves measured for dichloromethane in the presence of water indicate that a rapid increase in relative humidity can displace large quantities of dichloromethane from the adsorbed phase resulting in effluent streams containing more than 20 times the feed concentration. Additionally, the breakthrough time for organic compounds is reduced significantly at high relative humidity. Numerical simulation results show favorable qualitative agreement with measured breakthrough curves, yet do not consistently predict accurate water or dichloromethane loadings at all experimental conditions.