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The optimization of the vaporization and mixture formation process is of great importance for the development of modern gasoline direct injection (GDI) engines, because it influences the subsequent processes of the ignition, combustion and pollutant formation significantly. In consequence, the subject of this work was the development of a measurement technique based on the laser induced exciplex fluorescence (LIF), which allows the two dimensional visualization and quantification of the in-cylinder air/fuel ratio. A tracer concept consisting of benzene and triethylamine dissolved in a non-fluorescent base fuel has been used. The calibration of the equivalence ratio proportional LIF-signal was performed directly inside the engine, at a well known mixture composition, immediately before the direct injection measurements were started.

Mie-Scattering and laser induced exciplex fluorescence (LIEF) were used to visualize the distribution of liquid fuel and fuel vapor inside an optical accessible one-cylinder research engine with gasoline direct injection (GDI). Using a tracer which was developed especially for the environments of gasoline combustion engines, LIEF enables an extensive separation between liquid and vapor phase and delivers a signal proportional to the equivalence ratio. Simultaneous images of LIEF and Mie scattering proof the high quality of the phase separation using this tracer concept. The mixture formation process will be shown exemplary at one operation point with homogeneous load and another with stratified load. First results of determining the air/fuel ratio by means of linear Raman spectroscopy will be presented and compared with the two-dimensional qualitative distribution of the fuel vapor (LIEF).

Two-dimensional Mie and LIEF techniques were applied to investigate the spray propagation, mixture formation and charge distribution at ignition time inside the combustion chamber of a direct injection SI engine. The results obtained provide the propagation of liquid fuel relative to the piston motion and visualize the charge distribution (liquid fuel and fuel vapor) throughout the engine process. Special emphasis was laid on the charge distribution at ignition time for stratified charge operation. By means of a LIEF technique it was possible to measure cyclic fluctuations in the fuel vapor distributions which explain the occurrence of misfiring.

Two-dimensional Mie and LIEF techniques were applied to investigate the spray formation of a high pressure gasoline swirl injector in a constant volume chamber. The results obtained provide information on the propagation of liquid fuel and fuel vapor for different fuel pressures and ambient conditions. Spray parameters like tip penetration, cone angles and two new defined parameters describing the radial fuel distribution were used to quantify the fuel distributions measured. Simultaneous detection of liquid and vapor fuel was applied to study the influence of ambient temperature, injector temperature and ambient pressure on the evaporating spray.