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Technical Paper

High Cell Density Flow Through Substrate for New Regulations

2023-04-11
2023-01-0359
This paper, written in collaboration with Ford, evaluates the effectiveness of higher cell density combined with higher porosity, lower thermal mass substrates for emission control capability on a customized, RDE (Real Driving Emissions)-type of test cycle run on a chassis dynamometer using a gasoline passenger car fitted with a three-way catalyst (TWC) system. Cold-start emissions contribute most of the emissions control challenge, especially in the case of a very rigorous cold-start. The majority of tailpipe emissions occur during the first 30 seconds of the drive cycle. For the early engine startup phase, higher porosity substrates are developed as one part of the solution. In addition, further emission improvement is expected by increasing the specific surface area (GSA) of the substrate. This test was designed specifically to stress the cold start performance of the catalyst by using a short, 5 second idle time preceding an aggressive, high exhaust mass flowrate drive cycle.
Technical Paper

Achieving SULEV30 Regulation Requirement with Three-Way Catalyst on High Porosity Substrate while Reducing Platinum Group Metal Loading

2022-03-29
2022-01-0543
Fleet average SULEV30 emissions over FTP-75 must be met under full implementation of US Tier 3/LEV III emission regulation in 2025. The majority of SULEV30 certified 2021 model year vehicles are equipped with ≤ 2L displacement engines and some models adopt hybrid powertrain systems. Pickup trucks account for > 20% of passenger vehicles in the US. They could represent a quick route to meet fleet average SULEV30 targets. The newest pickup truck models are typically ULEV50 or ULEV70 certified. To reach SULEV30 or lower emission category, total tailpipe emissions must be reduced by more than 40%. Improvement of cold start emission is essential because over 70% of regulated emission is emitted during the first 60 seconds of a drive cycle with current engine and aftertreatment technology. High porosity (HP) ceramic substrate is designed to reduce thermal mass and time required to reach three-way catalyst (TWC) active temperature compared to conventional ceramic substrates.
Technical Paper

Development of Improved SCRonDPF Design for Future Tighter Regulations and Reduced System Packaging

2018-04-03
2018-01-0344
With the push towards more stringent on-road US heavy duty diesel regulations (i.e. HD GHG Phase 2 and the proposed ARB 20 mg/bhp-hr NOx), emission system packaging has grown critical while improving fuel economy and NOx emissions. The ARB regulations are expected to be implemented post 2023 while regulation for EU off-road segment will begin from 2019. The regulation, called Stage V, will introduce particle number (PN) regulation requiring EU OEMs to introduce a diesel particulate filter (DPF) while customer demands will require the OEMs to maintain current emission system packaging. A viable market solution to meet these requirements, especially for EU Stage V being implemented first, is a DPF coated with a selective catalyst reduction (SCR) washcoat (i.e. SCRonDPF).
Technical Paper

Alternative Particle Number Filtration Performance Test Method

2017-03-28
2017-01-0983
Particle Number (PN) regulation was firstly introduced for European light-duty diesel vehicles back in 2011[1]. Since then, PN regulation has been and is being expanded to heavy-duty diesel vehicles and non-road diesel machineries. PN regulation will also be expanded to China and India around 2020 or later. Diesel Particulate Filter (DPF) is significant factor for the above-mentioned PN regulation. This filter technology is to be continuously evolved for the near future tighter PN regulation. Generally, PN filtration performance test for filter technology development is carried out with chassis dynamometer, engine dynamometer or simulator [2]. This paper describes a simplified and relatively quicker alternative PN filtration performance test method for accelerating filter technology development compared to the current test method.
Technical Paper

Evaluation of Hydrothermally Aged Vanadia SCR on High-Porosity Substrate

2016-10-17
2016-01-2320
Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.
Technical Paper

High-Porosity Cordierite Honeycomb Substrate Design Parameter Study in Combination with Vanadia SCR

2016-04-05
2016-01-0949
Ammonia Selective Catalytic Reduction (SCR) is a key emission control component utilized in diesel engine applications for NOx reduction. There are several types of SCR catalyst currently in the market: Cu-Zeolite, Fe-Zeolite and Vanadia. Diesel vehicle and engine manufacturers down select their production SCR catalyst primarily based on vehicle exhaust gas temperature operation, ammonia dosing strategy, fuel quality, packaging envelope and cost. For Vanadia SCR, the operating temperature is normally controlled below 550oC to avoid vanadium sublimation. In emerging markets, the Vanadia SCR is typically installed alone or downstream of the DOC with low exhaust gas temperature exposure. Vanadia SCR is also utilized in some European applications with passive DPF soot regeneration. However, further improvement of Vanadia SCR NOx conversion at low exhaust gas temperatures will be required to meet future emission regulations (i.e.: HDD Phase 2 GHG).
Technical Paper

Design Optimization of Non-Catalyzed DPF from Viewpoint of Back Pressure in Ash loading State

2011-08-30
2011-01-2091
Back pressure of Diesel Particulate Filter (DPF) varies with accumulation of soot and/or ash. Soot can be cleaned in a high temperature oxidation (regeneration) process. But ash which is incombustible particulate matter derived from lubricant oil, engine wear, etc. cannot be cleaned from DPF without mechanical ash removal process and influences the back pressure perpetually. Design and control of DPF involving variation of the back pressure with ash accumulation will provide further improvement of fuel consumption and reliable operation in extended vehicle life time. Nevertheless, empirical investigations concerning ash accumulation are few because of the long testing time due to the slow accumulation rate, i.e. 0.5 - 2mg/mile [19]. In this investigation, four different designs of Cordierite (Cd) DPF were subjected to an accelerated ash accumulation test which is utilizing artificial ash powder.
Technical Paper

Development of Artificial Ash Accelerated Accumulation Test Method

2010-10-25
2010-01-2171
Ash accumulation is a considerable factor for long-term Diesel Particulate Filter (DPF) performance. Ash accumulation reduces the open frontal area (OFA) and plugs the surface pores. As a result, DPF back pressures with no soot (hereinafter “initial DPF back pressure”) rise. At the same time, DPF back pressures with soot (hereinafter “sooted DPF back pressure”) fall [ 1 , 2 , 3 , 4 ]. Then sooted DPF back pressures rise after the reductions of the certain ranges [ 1 , 3 , 4 ]. It is known that DPF back pressure behaviors change variously by ash loading like this. The understanding of DPF back pressure behaviors with ash accumulation is indispensable for proper after-treatment system management. Ash accumulation progresses slowly and gradually in DPF while using of vehicles. Because of the slowness, the field surveys require a few years at least.
Technical Paper

Studies of Diesel Particulate Filter Performances by a Diesel Engine Simulator

2010-04-12
2010-01-0813
To evaluate various Diesel Particulate Filter (DPF) efficiently, accelerated tests are one of effective methods. In this study, a simulator composed by diesel fuel burners is proposed for fundamental DPF evaluations. Firstly particle size distribution measurement, chemical composition and thermal analysis were carried out for the particulate matter (PM) generated by the simulator with several combustion conditions. The PMs generated by specific conditions showed similar characteristics to PMs of a diesel engine. Through these investigations, mechanism of PM particle growth was discussed. Secondly diversified DPFs were subjected to accelerated pressure drop and filtration efficiency tests. Features of DPFs could be clarified by the accelerated tests. In addition, the correlation between DPF pressure drop performance and PM characteristics was discussed. Thirdly regeneration performance of the simulator's PM was investigated.
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