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In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.

Engine technologies using efficient combustion and down-sizing turbo have become important in order to reduce automotive CO2 emissions. However, the exhaust gas temperature also becomes lower by these technologies. As a result, the catalyst performance becomes lower. Therefore it is necessary to develop low temperature active catalysts to reduce emissions. This research was focused on Pd/CeO2, and it’s able to oxidize CO at low temperatures. In order to increase the catalyst activity, the addition of some elements to the CeO2 was studied. Zn addition was found to have an advantage to reduce the CO light off temperature by 60 °C. Then, we tried to clarify the cause of improvement. As a result, it made clear that the Zn addition promotes the active oxygen release from the CeO2 surface. However, repeated engine exhaust gas tests indicated a decline in purification performance.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.

In recent years, automobile emission limits have been tightened world wide. PZEV (Partial Zero Emission Vehicle) which is the most stringent regulation has been imposed in California. To meet the strict PZEV regulation, automotive manufacturers are requesting the catalyst system to have quick light-off characteristics and excellent steady state performance with limited precious group metals (PGM) usage due to the strong price pressure. Moreover, the catalyst can not use high cell density substrate for increasing geometric surface area and reducing heat mass, since the backpressure of exhaust system must be decreased to improve the vehicle power for the PZEV application. This paper will present an efficient catalyst formulation that has been designed to maximize the performance with considerably reduce PGM loading. The catalyst washcoat has been optimized by improving the catalyst geometric surface area, gas diffusivity and thermal mass.

The orientation of electrodeposited Pb alloy crystal was related to the morphology of the deposits, and the orientated electrodeposits of a Pb alloy mainly consisting of the (h00) plane have exhibited a good wetness characteristic for lubricant oil. As a result, the orientated electrodeposits of this Pb alloy used in the overlay of bearings has an anti-seizure parameter (PV) at least 30% higher than that of conventional deposits in terms of the sliding characteristic. The sintered lead-bronze alloy used as the bearing's lining material offers good fatigue strength, which was made possible by adopting a newly developed Cu-Sn alloy matrix and reducing the amount and grain size of the Pb phase. Studies on plane bearings of high performance have clarified through bearing characteristic and engine firing tests that combining the orientated Pb alloy overlay and strengthening the lining increases the anti-seizure property and improves durability with regard to bearing fatigue and wear.