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In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.

Clarifying the impact of ETBE 8% blended fuel on current Japanese gasoline vehicles, under the Japan Clean Air Program II (JCAPII) we conducted exhaust emission tests, evaporative emission tests, durability tests on the exhaust after-treatment system, cold starting tests, and material immersion tests. ETBE 17% blended fuel was also investigated as a reference. The regulated exhaust emissions (CO, HC, and NOx) didn't increase with any increase of ETBE content in the fuel. In durability tests, no noticeable increase of exhaust emission after 40,000km was observed. In evaporative emissions tests, HSL (Hot Soak Loss) and DBL (Diurnal Breathing Loss) didn't increase. In cold starting tests, duration of cranking using ETBE 8% fuel was similar to that of ETBE 0%. In the material immersion tests, no influence of ETBE on these material properties was observed.

Biomass derived fuel is regarded as a carbon neutral fuel. Therefore, biomass ethanol is thought to be a promising gasoline blend stock to reduce CO2 emissions from vehicles, and its practical use is under discussion. However, there are many considerations for blending ethanol into conventional gasoline. One of the important considerations is a vapor pressure rise of the gasoline that might cause an increase in evaporative emissions from ethanol-blended gasoline. This study examines and discusses the effects of ethanol-blended gasoline on evaporative emissions, especially on refueling and running loss (RL) emissions. Furthermore, in addition to ethanol, the use of ETBE (Ethyl tert-Butyl Ether), which is synthesized from biomass ethanol and isobutene, is also under discussion in Japan. Therefore, the effects of ETBE on evaporative emissions were also examined and compared to ethanol effects.

An attempt to reduce the HC emission of a two-stroke engine was carried out. A simple homogeneous charge combustion created with a Direct Fuel Injection (DFI) system was applied to a Personal Water Craft (PWC) engine. 1/4 HC emission of the base carbureted engine was obtained in International Council of Marine Industry Association (ICOMIA) driving mode due to the exclusion of fuel short-circuiting. Then stratified charge combustion was introduced. A numerical simulation of air and spray motion was performed and mixture formation was optimized. The low load misfiring was completely overcome and finally, less than 1/8 HC emission was achieved.

Worldwide concern about combustion chamber deposits (CCDs) has increased from the viewpoint of fuel and additives technology, which has been developed for the cleaning of intake valve deposits (IVDs), intake port deposits and injector deposits. The research effort described here, focused on the differences between CCDs and IVDs in terms of quality based on analyses of CCDs and IVDs collected from used vehicles from the Japanese market. The CCDs and IVDs were characterized according to weight, benzene-solubles and sulfated ash. Since the sulfated ash in CCDs is a key to understanding the effect of engine oil on CCD formation, the relationship between CCDs and the sulfated ash in CCDs was evaluated under the two typical conditions on a 2.0L engine testing bench. Based on the results, the gasoline-related and oil-related factors were estimated for these conditions. Moreover, the effect of CCDs on exhaust emissions was investigated in a 2.2L vehicle.

The effects of gasoline volatility (T50 and T90), sulfur content and hydrocarbon types on CO, NOx, total hydrocarbon and speciated hydrocarbons were investigated. The properties of the test gasoline were varied in the range of the Japanese marketplace gasoline, which are characterized by low T50, T90 and low sulfur content. Sulfur content is, especially, regulated under 100 ppm. The Japanese 10.15 mode emissions under hot-transient conditions were measured by using a vehicle equipped with a three-way catalyst. The results indicated that the sulfur content was more effective on exhaust CO, total hydrocarbon and NOx emissions than T50, T90 or hydrocarbon types of gasoline were. The sensitivity to sulfur was different depending on the speciated hydrocarbons. Increasing the sulfur content significantly raised exhaust paraffines, but had no significant effect on olefins. Among the aromatics, the exhaust benzene was most sensitive to sulfur.

Recently, an audible clattering noise has been noticed in some vehicles during cold engine starts, mainly in the U.S. The clattering is referred to by various names, such as “carbon knock,” “carbon rap,” “mechanical knock” and “combustion chamber deposit interference (CCDI).” CCDI is believed to be caused by the deposit formation in the combustion chamber. In the research effort described here, CCDI was successfully reproduced in a 2.5-liter multipoint injection engine with a polyolefin amine gasoline additive. It was determined that the CCDI was caused by mechanical contact between the piston top and the cylinder head deposits. The vibration due to CCDI originated mainly at the thrust side of the piston right after top-dead-center on compression stroke and was characterized by a high frequency response. Combustion chamber deposit (CCD) formation depends on many factors, including gasoline additives.