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Effects of temperature, pressure and global equivalence ratio on total ignition delay time in a constant volume spray combustion chamber were investigated for diesel fuel along with the primary reference fuels (PRFs) of n-heptane and iso-octane in relatively low temperature conditions to simulate unsteady spray ignition behavior. A KAUST Research ignition quality tester (KR-IQT) was utilized, which has a feature of varying temperature, pressure and equivalence ratio using a variable displacement fuel pump. A gradient method was adopted in determining the start of ignition in order to compensate pressure increase induced by low temperature heat release. Comparison of this method with other existing methods was discussed. Ignition delay times were measured at various equivalence ratios (0.5-1.7) with the temperatures of initial charge air in the range from 698 to 860 K and the pressures in the range of 1.5 to 2.1 MPa, pertinent to low temperature combustion (LTC) conditions.

The focus on fuel efficiency, performance, and the regulatory requirements of emissions have brought the attentions on injection strategies for improvement of in-cylinder mixture preparation and elimination of the sources of combustion emissions, in particular the in-cylinder particulate formation. In this paper, with the focus on better fuel efficiency and reduction of emissions, high-pressure and split injection strategies were investigated in a single cylinder DI diesel engine. It provides results of a study of the influence of fuel pressure increase between 30 to 180 MPa, in conjunction with the main injection events split in two or three, on the combustion characteristics, specifically the particulate and gaseous emissions and the fuel economy. The experimental data shows the marked effect of fuel pressure increase on reduction of the particulate emissions.

Methyl tert-butyl ether (MTBE) was added to diesel fuel to investigate the effect on ignition delay and soot oxidative reactivity. An ignition quality tester (IQT) was used to study the ignition propensity of MTBE blended diesel fuels in a reactive spray environment. The IQT data showed that ignition delay increases linearly as the MTBE fraction increases in the fuel. A four-stroke single cylinder diesel engine was used to generate soot samples for a soot oxidation study. Soot samples were pre-treated using a tube furnace in a nitrogen environment to remove any soluble organic fractions and moisture content. Non-isothermal oxidation of soot samples was conducted using a thermogravimetric analyzer (TGA). It was observed that oxidation of ‘MTBE soot’ started began at a lower temperature and had higher reaction rate than ‘diesel soot’ across a range of temperatures.

An experimental study on effects of high-pressure injections in conjunction with split fuel injections were conducted on an AVL single cylinder DI diesel engine. Various injection schemes were studied through the use of an electronically controlled, common rail injection system capable of injection pressures up to 200 MPa and a maximum of six injections per combustion event. Up to 100 MPa of the fuel injection pressure, the higher injection pressures create faster combustion rates that result in the higher in-cylinder gas temperatures as compared to conventional low-pressure fuel injection systems. When applying high-pressure injections, particulate emission reductions of up to 50% were observed with no change in hydrocarbon emissions, reductions of CO emissions and only slightly higher NOx emissions. Over 100 MPa, on the other hand, the higher injection pressures still reduced up to almost zero-level of particulate emission, at the same time that the NO emission is reduced greatly.

A reduced chemical kinetic mechanism for a gasoline surrogate was developed and validated in this study for CAI (Controlled Auto Ignition) combustion. The gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. This reduced mechanism consisted of 44 species and 59 reactions, including main reaction paths of iso-octane, n-heptane, and toluene. The ignition delay times calculated from this mechanism showed a good agreement with previous experimental data from shock tube measurement. A rapid compression machine (RCM) was developed and used to measure the ignition delay times of gasoline and surrogate fuels in the temperature range of 890K ∼ 1000K. The RCM experimental results were also compared with the RCM simulation using the reduced mechanism. It was found that the chemical reaction started before the end of the compression process in the RCM experiment. And the ignition delay time of the suggested gasoline surrogate was similar to that of gasoline.

The effect of secondary air injection (SAI) on exhaust hydrocarbon (HC) emission has been investigated in a spark-ignition (SI) single cylinder engine operating at steady-state cold condition. Both continuous SAI and synchronized SAI, which corresponds to intermittent secondary air injection to exhaust port, are tested. Oxidation characteristics of HC are monitored with a FID analyzer and exhaust gas temperatures with thermocouples. Effects of exhaust air-fuel ratio (A/F), location of SAI, and engine-A/F have been investigated. Results show that HC reduction rate increases as the location of SAI is closer to the exhaust valve for both synchronized and continuous SAIs. HC emission decreases with increasing exhaust-A/F when exhaust-A/F is rich, and is relatively insensitive when exhaust-A/F is lean. In synchronized SAI, SAI timing has significant effect on HC reduction and exhaust gas temperature. Optimum SAI timing observed is ATDC 100° and 230°.