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In practical applications of ammonia SCR aftertreatment systems using urea as the reductant storage compound, one major difficulty is the often constrained packaging envelope. As a consequence, complete mixing of the urea solution into the exhaust gas stream as well as uniform flow and reductant distribution profiles across the catalyst inlet face are difficult to achieve. This paper discusses a modeling approach, where a combination of 3D CFD and a lumped parameter SCR model enables the prediction of system performance, even with non-uniform exhaust flow and ammonia distribution profiles. From the urea injection nozzle to SCR catalyst exit, each step in the modeling process is described and validated individually. Finally the modeling approach was applied to a design study where the performance of a range of urea-exhaust gas mixing sections was evaluated.

A test method, based on parallel sample testing with exhaust fuel injection and certain test procedures, has been developed for diesel lean-NOx catalyst evaluation purposes. The results of the verification tests show uniform distribution of both the exhaust gas and the injected fuel, and a high degree of fuel evaporation. Test procedures are discussed from several points of view. The test method offers a precise and efficient way of testing lean-NOx catalysts on heavy duty diesel engines.

The catalytic converter on a European diesel car must operate under extremely variable conditions, ranging from very low temperature during city-driving to high temperature during Autobahn-driving. Therefore, the development of new catalyst technology for European applications requires simultaneous achievement of properties that have long been considered incompatible. In this paper, it is shown how extremely good low temperature activity for CO and hydrocarbons (and VOF), negligible storage of sulfates, and very good thermal durability were obtained simultaneously with an appreciable reduction of NOx. Through the systematic analysis of basic catalytic phenomena, under conditions of relevance to the real-world application, it was possible to control the interaction between support, stabilizers and promoters with the precious metal package in an efficient way. The large-scale manufacturing aspects formed an important part of the development program.