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Semi-volatile organic compounds (SVOC) are a group of compounds that may form during combustion and/or are present in the unburned portion of the fuel and lubricating oil which ultimately become part of the exhaust. Many of these compounds are considered toxic or carcinogenic. Since these compounds are present in very low concentrations in diesel engine exhaust, the methods for sampling, handling, and analyzing these compounds are critical to obtaining representative and repeatable results. Engine testing is typically performed using a dilution tunnel. With a dilution tunnel, the collection of a representative sample is important. Experiments were performed with a modified EPA Method TO-9A to determine the equilibration time and other sampling parameters required for the measurement of SVOC in dilute exhaust. The results show that representative results can be obtained with this method.

Enhancement of fuel/air mixing is one path towards enabling future diesel engines to increase efficiency and control emissions. Air-assist fuel injections have shown potential for low pressure applications and the current work aims to extend air-assist feasibility understanding to high pressure environments. Analyses were completed and carried out for traditional high pressure fuel-only, internal air-assist, and external air-assist fuel/air mixing processes. A combination of analytical 0-D theory and 3D CFD were used to help understand the processes and guide the design of the air-assisted setup. The internal air-assisted setup was determined to have excellent liquid fuel vaporization, but poorer fuel dispersion than the traditional high-pressure fuel injections.

The US EPA emission standards for 2010 on-highway and 2014 non-road diesel engines are extremely stringent, both in terms of oxides of nitrogen (NOX) and particulate matter (PM). Diesel engines typically operate lean and use at least 40-50 percent more air than what is needed for stoichiometric combustion of the fuel. As a result, significant excess oxygen (O₂) is present in diesel exhaust gas which prevents the application of the mature three-way catalyst (TWC) technology for NOX control used in gasoline engines. The objective of this work was to investigate whether or not the catalyzed DPF had a TWC-type of effect on NOX emissions and if so, why and to what extent when used on a diesel engine operating at reduced A/F ratio conditions.

Manufacturers of heavy-duty diesel engines for sale in the United States face an unprecedented reduction in emissions in 2007 and in 2010. Compared to today's levels, a 90% reduction in particulate matter (PM) must be achieved by 2007, and a 90% reduction in nitric oxides (NOx) must be achieved by 2010. This paper focuses on the technology solutions possible for engine makers for the interim 2007-2009 timeframe and discusses the additional NOx reduction strategies for a 2010 compliant engine. The possibility of achieving a larger portion of the interim 2007-2009 NOx standard through in-cylinder control methods rather than by NOx exhaust treatment is discussed. High levels of exhaust gas recirculation (EGR) and advanced injection strategies to modify the conventional diesel combustion process are just two processes that can be accommodated in many of today's engine designs.

An experimental investigation of partial premixed charge compression ignition (PCCI) in combination with direct fuel injection was conducted on a Caterpillar C-15 heavy-duty diesel engine (HDDE). The intent of the program was to investigate the performance, emissions, and efficiency characteristics of the concept. A portion of the fuel was delivered to the intake manifold using air-assist port fuel injectors. The spray droplet characteristics were measured, for several different injector geometries, over a range of thermodynamic conditions. Subsequently, the optimized port fuel injector (PFI) was utilized in the engine tests. The engine tests were run at conditions ranging from 1200 - 1800 RPM, loads ranging from 25 - 75%, and PFI quantities ranging from approximately 10 - 70%. The tests showed that oxides of Nitrogen (NOX) emissions did not decrease dramatically with partial premixing.

An experimental investigation of the effects of partial premixed charge compression ignition (PCCI) combustion and EGR temperature was conducted on a Caterpillar C-12 heavy-duty diesel engine (HDDE). The addition of EGR and PCCI combustion resulted in significant NOx reductions over the AVL 8-mode test. The lowest weighted BSNOx achieved was 2.55 g/kW-hr (1.90 g/hp-hr) using cooled EGR and 20% port fuel injection (PFI). This represents a 54% reduction compared to the stock engine. BSHC and BSCO emissions increased by a factor of 8 and 10, respectively, compared to the stock engine. BSFC also increased by 7.7%. In general, BSHC, BSCO, BSPM, and BSFC increased linearly with the amount of port-injected fuel.