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Technical Paper

Detailed Chemical Composition and Particle Size Assessment of Diesel Engine Exhaust

2002-10-21
2002-01-2670
A dilution source sampling system has been incorporated into the exhaust measurement system of a research single-cylinder diesel engine. To allow more detailed assessment of the individual chemical components of the diesel particulate matter (PM) the exhaust dilution system includes a residence time chamber (RTC) to allow for residence times of 30 to 60 seconds in the second stage of dilution before sampling. Samples are collected on a range of different filters where mass loading, elemental and organic carbon (ECOC), trace metals, sulfate ions (SO4), particle-phase organic compounds, and semi-volatile organic compounds are evaluated. In addition, particle size distributions have been determined using a scanning mobility particle sizer (SMPS). Results show that the chemical composition of the particulate matter is highly dependent on the engine operating conditions.
Technical Paper

Effect of Engine Operating Conditions on Particle-Phase Organic Compounds in Engine Exhaust of a Heavy-Duty Direct-Injection (D.I.) Diesel Engine

2003-03-03
2003-01-0342
Significant amounts of particle-phase organic compounds are present in the exhaust of diesel vehicles. It is believed that some of these compounds have a greater impact on human health and the environment than other compounds. Therefore, it is of significant importance to speciate particle-phase organic compounds of diesel particulate matter (PM) to clarify the effects of PM on human health and the environment, and to understand the mechanisms of organic compounds formation in PM. A dilution source sampling system was incorporated into the exhaust measurement system of a single-cylinder heavy-duty direct-injection (D.I.) diesel engine. This system was designed specifically to collect fine organic aerosols from diesel exhaust. The detailed system is described in Kweon et al. [27].
Technical Paper

Effect of Fuel Composition on Combustion and Detailed Chemical/Physical Characteristics of Diesel Exhaust

2003-05-19
2003-01-1899
An experimental study was performed to investigate the effect of fuel composition on combustion, gaseous emissions, and detailed chemical composition and size distributions of diesel particulate matter (PM) in a modern heavy-duty diesel engine with the use of the enhanced full-dilution tunnel system of the Engine Research Center (ERC) of the UW-Madison. Detailed description of this system can be found in our previous reports [1,2]. The experiments were carried out on a single-cylinder 2.3-liter D.I. diesel engine equipped with an electronically controlled unit injection system. The operating conditions of the engine followed the California Air Resources Board (CARB) 8-mode test cycle. The fuels used in the current study include baseline No. 2 diesel (Fuel A: sulfur content = 352 ppm), ultra low sulfur diesel (Fuel B: sulfur content = 14 ppm), and Fisher-Tropsch (F-T) diesel (sulfur content = 0 ppm).
Technical Paper

Effect of Injection Timing on Detailed Chemical Composition and Particulate Size Distributions of Diesel Exhaust

2003-05-19
2003-01-1794
An experimental study was carried out to investigate the effects of fuel injection timing on detailed chemical composition and size distributions of diesel particulate matter (PM) and regulated gaseous emissions in a modern heavy-duty D.I. diesel engine. These measurements were made for two different diesel fuels: No. 2 diesel (Fuel A) and ultra low sulfur diesel (Fuel B). A single-cylinder 2.3-liter D.I. diesel engine equipped with an electronically controlled unit injection system was used in the experiments. PM measurements were made with an enhanced full-dilution tunnel system at the Engine Research Center (ERC) of the University of Wisconsin-Madison (UW-Madison) [1, 2]. The engine was run under 2 selected modes (25% and 75% loads at 1200 rpm) of the California Air Resources Board (CARB) 8-mode test cycle.
Technical Paper

Measurement of Trace Metal Composition in Diesel Engine Particulate and its Potential for Determining Oil Consumption: ICPMS (Inductively Coupled Plasma Mass Spectrometer) and ATOFMS (Aerosol Time of Flight Mass Spectrometer) Measurements

2003-03-03
2003-01-0076
Current regulations stipulate acceptable levels of particulate emissions based on the mass collected on filters obtained by sampling in diluted exhaust. Although precise, this gives us only aggregated information. If in addition to the mass based measurements, detailed chemical analysis of the particulate matter (PM) is performed, additional subtle information about the combustion process can be revealed. This paper reports the results of detailed chemical analysis of trace metal in the PM emitted from a single cylinder heavy-duty diesel engine. The trace metal concentrations are used as an indicator of oil consumption. Two techniques were used to make the trace metal concentration measurements. PM was captured on filters and trace metals were quantified with an Inductively Coupled Plasma Mass Spectrometer (ICPMS), and also an Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) was used to perform particle size and composition measurements in real time.
Technical Paper

Particulate Matter Emission in steady state operation and transient operation from Direct Injection (DI) Off-Road Diesel Engine

2005-09-11
2005-24-017
For protecting human health and preserving the clean environment, current regulations stipulate acceptable levels of particulate emissions based on the mass collected on filters obtained by sampling in diluted exhaust. Such regulations will be imposed not only on-road engines but also off-road engines. From the point of view of human health [1], so-called nano-particle (d<50nm) is thought to be nuisance because it could reach deeper lung tissue. So, many researches have been done in this research field [2]. A series of experiments were conducted on an off-road general purpose direct Injection (DI) diesel engine using EEPS (Engine Exhaust Particle Sizer) to make real time particle size distribution measurements possible. The data presented covers whole operating conditions including the operating modes of off-road diesel engine emission test (C1mode). Additionally, PM emissions in transient (NRTC test cycle) engine operation were examined.
Technical Paper

The Effect of Compression Ratio on Low Soot Emission from a Small Non-Road Diesel Engines

2013-09-08
2013-24-0060
Particulate matter (PM) emission of non-road diesel engines is more and more stringently restricted by US, EU, Japan, etc. In order to achieve these emission regulations, diesel particulate filter (DPF) system is applied. However DPF system requires extra fuel consumption in order to burn accumulated particles. Furthermore, since it is difficult to install large DPF systems in limited packaging space of non-road applications, compact DPF system is desirable. Reducing soot emission with engine technology is effective for reducing PM emission, which results in reducing extra fuel consumption and downsizing or removing of DPF system. Soot emission level mainly depends on excess air ratio (EAR), and can be reduced by keeping EAR high (lean combustion). However, lean combustion under the limited amount of air and maximum in-cylinder pressure requires decrease in fuel injection quantity, and yields decrease in engine power.
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