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The purpose of this paper is to find a way to extend the high load limit of homogeneous charge compression ignition (HCCI) combustion. This paper presents the effect of in-cylinder flow and stratified mixture on HCCI combustion by experiments and three-dimensional computer fluid dynamics coupled with a detailed chemical reaction calculation. The first study was conducted using a rapid compression and expansion machine (RCEM) equipped with a flow generation plate to create in-cylinder turbulent flow and with a control unit of in-cylinder wall temperature to create in-cylinder temperature distribution. The study assesses the effect of the turbulent flow and the temperature distribution on HCCI combustion. In the second study, the numerical simulation of HCCI combustion was conducted using large eddy simulation coupled with a detailed chemical reaction calculation. The study analyzes the interaction between in-cylinder turbulent flow and mixture distribution and HCCI combustion.

It has been widely known that thermal and fuel stratifications of in-cylinder mixture are effective to reduce in-cylinder pressure rise rate during high load HCCI operations. In order to optimize a combustion chamber design and combustion control strategy for HCCI engines with wide operational range, it is important to know quantitatively the influence of the temperature and fuel concentration distributions on ignition and heat release characteristics. At the same time, it is important to know the influence of in-cylinder flow and turbulence on the temperature and fuel concentration distributions. In this study, a numerical simulation of HCCI combustion were conducted to investigate the effects of the in-cylinder flow and turbulence, and the distributions of temperature on ignition and combustion characteristics in HCCI combustion.

The environmental temperature where vehicles are used varies significantly by region and season, so this study investigated the influence of environmental temperature on the fatigue life of compressed hydrogen tanks for vehicles (Type 3). Pressure-cycle tests with varying environmental temperature were conducted on tanks until the tank was failed. Results indicated that fatigue life decreased in low-temperature environments and improved in high-temperature environments. We investigated the cause of such results using the strains inside and outside the tank and other indexes and found that the effect of autofrettage varied as environmental temperature changed, due to the difference between the thermal expansion rate of CFRP and that of aluminum alloy. Thus, we concluded that fatigue life changed according to changes in environmental temperature.

In this study, hydrogen was leaked using a nozzle that simulated an actual leak port (with varied materials and diameters), and the possibility of ignition was verified to collect data useful for establishing standards for the allowable flow rate of hydrogen leakage on receptacle. With the flow rate of a hydrogen leak set at 250 mL/h(NTP) (hereinafter mL/h is NTP condition) or less, ignition of leaked hydrogen with an electric spark and a small methane-fueled flame was attempted. The results confirmed that ignition of 200 mL/h of hydrogen was not achieved under tested conditions. In some cases, hydrogen at a flow rate of 250 mL/h was ignited. Tissue paper placed in contact with the flame at a flow rate of 250 mL/h combusted, resulting the flame went out almost immediately. Therefore, it was determined that a hydrogen leak at approximately 200 mL/h that occurred in this test is a very low possibility of ignition or spreading.

The hydrogen consumption of fuel cell vehicles (FCV) can be measured by the gravimetric, pressure and flow methods within a ±1% error. These are the methods acknowledged by ISO and SAE [1, 2], but require the test vehicles to be modified in order to supply hydrogen from an external, rather than the onboard tank. Consequently, technical assistance of the vehicle manufacturer is necessary for this modification, while various components in the test vehicle must be readjusted. For these reasons, a measurement method free of vehicle modification is in great demand. The present study therefore developed an “oxygen balance method” which determines the amount of hydrogen that has reacted with oxygen in the fuel cell stack by measuring the oxygen concentration in exhaust gas.

If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.

Concerning carbon monoxide, hydrogen sulfide and ammonia, which are likely to be present in hydrogen fuel as impurities, a study was conducted to evaluate the impact of these impurities on the performance of proton exchange membrane fuel cells (“PEMFC”). The study involved a fuel cell performance test using a single cell and the analysis of exhaust gases from the cell. The fuel cell was operated continuously for 10 hours under acceleration test conditions at a 1,000 mA/cm2 current density and a 17 % fuel gas utilization. The results: the cell performance declined when any of the three impurities was present at lower than ppm content levels (0.2 - 0.5 ppm) in hydrogen fuel. Pt-Ru alloy catalysts, known for their higher resistance than Pt to poisoning by carbon monoxide, failed to show improvement of resistance to poisoning by hydrogen sulfide and ammonia.

Japan Automobile Research Institute (JARI) have developed the flow method as an easy way of measuring hydrogen consumption of fuel cell vehicles (FCVs) in real-time. A 2004 study on fuel consumption of five models of FCVs, measured by thermal flowmeters and based on gravimetric method, exhibited measurement errors within ±1% range for three models, but the errors were as large as -8% for two models that showed significant pulsation in hydrogen consumption flow. Assuming that the pulsation is the cause of errors in the flow method, we analyzed influences of pulsation in each flowmeter from two points (frequency and amplitude) and found that pulsation indeed caused flowmeter errors. Expansion chambers (Buffers) and throttle valves (regulators) were confirmed to have an effect in attenuating pulsation. Amplitude of pulsation shrunk to one tenths when such pulsation-reducing instruments were introduced between pulsating FCVs and flowmeters and were put to test.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

Gas behavior during fast filling of a compressed gaseous hydrogen storage tank (Type 3, 35MPa) was simulated numerically to investigate in detail the resulting unsteady temperature distribution and its correlation with the storage tank conditions. The governing equations for the gas phase are the mass, momentum, and energy equations; these equations were discretized using the finite volume method (FVM) in three-dimensional space. The numerical results were carefully compared with the experiment results and have been validated. Consequently, the temperature distributions in space, the time histories of temperature at the measured points, and the filling time to the target pressure were all in good agreement. Furthermore, the unsteady gas and its thermal behavior were clearly visualized in three-dimensional space.

The purpose of this study is to clarify the influence of the maximum pressure on the lifetimes of compressed hydrogen tanks during ambient temperature pressure cycling tests. We varied the maximum pressure from 100% to 200% of designed filling pressure (FP) in five levels. Type 3 (Fully wrapped composite tank with metal liner): The tank's lifetimes, i.e. the numbers of cycles up to Leak Before Break (LBB), decreased with increasing maximum pressure. We observed that the internal surface of the liners had linear flaws resulting from the manufacturing process. Cracks causing LBB seemed to initiate from these flaws. Striation marks clearly appeared at the fracture surface of LBB cracks when the maximum pressure exceeded 125% of FP. Therefore, we suggest that LBB cracks were caused by a similar process of crack propagation in this range. In spite of the maximum pressure changes (100% to 200% of FP), tank strain was proportional to pressure at all times.

hydrogen was leaked from the underfloor at a flow rate exceeding 131 NL/min (11.8 g/min), which is the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, and the resulting distribution of concentration in the engine compartment and the dispersion after stoppage of the leak were investigated. Furthermore, ignition tests were also conducted and the impact on the surroundings (mainly on human bodies) was investigated to verify the safety of the allowable leakage rate. The tests clarified that if hydrogen leaks from the underfloor at a flow rate of 1000 NL/min (89.9 g/min) and is ignited in the engine compartment, people around the vehicle will not be seriously injure. Therefore, it can be said that a flow rate of 131 NL/min (11.8 g/min), the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, assures a sufficient level of safety.

The distribution of concentrations of hydrogen leaking into the front compartment and the dispersion after the leak was stopped were investigated to obtain basic data for specifying the mounting positions of hydrogen leak detecting sensors and the threshold values of alarms for compressed hydrogen vehicles. Ignition tests were also conducted to investigate the flammability and the environmental impact (i.e. the impact on human bodies). These tests were also conducted with methane to evaluate the protection against hydrogen leaks in vehicles in comparison with natural gas (methane). We found that the concentration of hydrogen in the front compartment reached 23.7 vol% maximum when hydrogen gas was allowed to leak for 600 sec from the center of the bottom of the wheelbase at a rate of 131 NL/min, which is the allowable limit for a fuel leak at the time of collision of compressed hydrogen vehicles in Japan.

To achieve a method for flame exposure testing of high-pressure cylinders in automobiles that allows fair evaluations to be made at each testing institute and also provides high testing accuracy, we investigated the effects of the flame scale of the fire source, the fuel type, the shape of the pressure relief device shield, and the ambient temperature through experiments and numerical simulation. We found that, while all of these are factors that influence evaluation results, the effects of some factors can be reduced by increasing the flame size. Therefore, a measurement technique to quantitatively determine the flame size during the test is required. Measuring temperatures at the top of each cylinder is a candidate technique. Furthermore, flame exposure tests to be conducted on cylinders as single units must ensure safety during a vehicle fire.

In this study, we evaluated the fire safety of vehicles that use compressed hydrogen as fuel. We conducted fire tests on vehicles that used compressed hydrogen and on vehicles that used compressed natural gas and gasoline and compared temperatures around the vehicle and cylinder, internal pressure of the cylinder, irradiant heat around the vehicle, sound pressure levels when the pressure relief device (PRD) was activated, and damage to the vehicle and surrounding flammable objects. The results revealed that vehicles equipped with compressed hydrogen gas cylinders are not more dangerous than CNC or gasoline vehicles, even in the event of a vehicle fire.

Japan Automobile Research Institute has devised and evaluated the various fuel consumption measurement methods for fuel cell vehicles (FCVs). The examination covers the methods based on measurement of electrical current, hydrogen pressure/temperature, weight and flow rate that are expected to be the same accuracy and convenience as conventional measurement methods such as carbon balance method or fuel flow measurement method. As a result of examining the measurement accuracy for each method with a sonic nozzle used as a standard, it is found that both the pressure method and the weight method fulfill the target accuracy of ±1% and that the flow method is able to improve the accuracy by means of calibration with hydrogen. Also, as a result of applying each method to the fuel consumption test of FCVs, the relative error between the pressure method and weight method is within ±1%.

To determine the appropriateness of specifying the allowable amount of hydrogen leakage upon collision based on the amount of leakage with generated heat equivalent to that of gasoline vehicles and CNG vehicles, we investigated the safety of each type of fuel when flame ignites. Our results confirm that the flame lengths for hydrogen and methane are almost equal, and there is no remarkable difference between them in terms of the distance for assuring safety. Furthermore, we confirmed that the irradiant heat flux from the mixed burning of hydrogen flame with liquid flammable materials is almost equal to that of the spray flame of gasoline. Thus, no clear difference was found between various types of fuel. Therefore, it is appropriate to specify the allowable amount of hydrogen leakage based on the amount of leakage with generated heat equivalent to that of other types of fuel.

To investigate methods of conducting flame exposure tests (bonfire tests) on high-pressure hydrogen gas cylinders that are safe and have high accuracy across repeated tests, we used numerical simulation and experiments to analyze the feasibility of using substitutive gases for filling as well as the effects of the burners used as the fire source. Through a series of virtual experiments using substitutive gases, flame scales, and filling pressure as parameters, we examined the maximum internal pressure, the rate of pressure rise, and the starting time of Pressure Relief Device (PRD) activation. Because substitutive gas properties differ from those of hydrogen gas, we concluded that using substitutive gases would be inappropriate. In addition, we observed that when the flame scale was small, the cylinder's internal pressure before the thermal-activated PRD activation, the rate of pressure rise, and the starting time of PRD activation all increased rapidly.

The high-pressure hydrogen gas cylinder of a fuel-cell vehicle is equipped with a pressure relief device (PRD) to prevent the rupture of the cylinder due to heating by fire. Flame exposure tests (bonfire tests) are conducted to evaluate the safety of the cylinder with the PRD, specifically, cylinder resistance to fire and performance of the PRD. In this study, however, fire tests of vehicles equipped with high-pressure cylinders were not required for this test method. We implemented released-hydrogen flame tests by performing bonfire tests and fire tests on vehicles equipped with hydrogen-filled high-pressure gas cylinders (20,35MPa) to examine safety measures for fuel-cell vehicles. We then investigated the following: the characteristics of the released-hydrogen flame, radiation heat flux from the jet flame, combustion noise, the rate of pressure rise in the cylinder, the venting direction of the PRD, and behavior of fire in conjunction with a gasoline flame.