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In order to investigate the effect of sulfur and distillation properties on exhaust emissions, emission tests were carried out using a California Low Emission Vehicle (LEV) in accordance with the 1975 Federal Test Procedure ('75 FTP). To study the fuel effect on the exhaust emissions from different systems, these test results were compared with the results obtained from our previous studies using a 92MY vehicle for California Tier 1 standards and a 94MY vehicle for California TLEV standards. (1)(2) First, the sulfur effect on three regulated exhaust emissions (HC, CO and NOx) was studied. As fuel sulfur was changed from 30 to 300 ppm, the exhaust emissions from the LEV increased about 20% in NMHC, 17% in CO and 46% in NOx. To investigate the recovery of the sulfur effect, the test fuel was changed to 30 ppm sulfur after the 300 ppm sulfur tests. The emission level did not recover to that of the initial 30 ppm sulfur during three repeats of the FTP.

When a thermoplastic boot is installed on a constant velocity joint (CVJ) which is set at an angle, the centerline of the boot shows a particular curve like S-shape in its axial direction. This S-curve varies according to the designed shape of boot. By studying the correlationship between the S-curve and the boot performance, it is found that a particular design of boot enhances its durability, which allows further reduction of the size of boot. This paper includes discussions on the correlation between the boot performance and the S-curve, and the durability test results of an ultra-small boot we have developed, together with the improvement of durability of polyester elastomer we have studied at the same time.

The 50% and 90% distillation temperature (T50 & T90), aromatics, olefins and sulfur content are regulated in California Phase2 Reformulated Gasoline. The effects of these properties on the exhaust emissions were investigated. Twelve test fuels with little interaction between T50, T90, aromatics and olefins were prepared. Exhaust emissions were measured using a TLEV according to 1975 Federal Test Procedure (75 FTP). T50 had a large effect on exhaust HC emissions. T90 also affected HC emissions. Both increasing and decreasing T50, T90 showed increasing exhaust HC emissions. These results suggest that an optimum range of T50 and T90 exist for lowering exhaust HC emissions. The effects of sulfur on exhaust emissions were also investigated. A Pt/Rh type catalyst (production type) and a Pd type catalyst (prototype) were prepared. These catalysts were put on a 94MY TLEV. Increase of sulfur lead to increase of the exhaust emissions with both catalysts.

It is widely known that pellet-typed catalysts are deactivated by phosphorus (ZnDTP) that comes from engine oils. In this paper, the poisoning of monolithic three-way catalysts and oxygen sensors by engine oils is studied. First, catalysts and oxygen sensors were poisoned on the engine bench by test oils in which the quantity of phosphorus and ash was varied. Next, performance of the catalysts and sensors alone was examined and the vehicle exhaust emission at FTP mode was measured on a chassis dynamometer. The results indicate that phosphorus in engine oils poisons the monolithic catalyst and the oxygen sensor resulting in deterioration of the vehicle NOx exhaust emission. However, Ca sulfonate and Mg sulfonate detergents act by restraining phosphorus poisoning of the catalyst and the oxygen sensor. Through analysis of the catalyst and sensor surfaces, it is concluded that phosphorus poisons the catalyst and sensor forming a dense coating.

Fuel economy is one of the most important performance features for modern engine oils. For some time now, fuel efficient engine oils (called Energy Conserving II or EC-II) have been available in the marketplace. However, the performance of EC-II oils is only 2.7% Equivalent Fuel Economy Improvement (EFEI) as measured by the ASTM Sequence VI Engine Test. To meet future industry needs, more fuel efficient engine oils are desirable. In order to achieve this, a study of highly fuel efficient engine oils was initiated. An initial target of 3.9% EFEI was selected and several candidate oils were evaluated, some of which exceeded this target. The oils were evaluated using a chassis dynamometer using the U. S. EPA mode. The test results may be summarized: 5W-30 Prototype Oil containing MoDTC showed between 1.6 and 2.6% better fuel economy than conventional 5W-30 and 10W-30 EC-II oils. There was an optimum viscosity for maximum fuel economy using the EPA testing mode.