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In this research we developed surface kinetic model with detailed reaction mechanisms for simulating reaction dynamics of NOx Storage& Reduction (NSR) Catalyst and three-way catalyst (TWC). Simulation results showed that surface site coverage strongly dominates catalytic reaction characteristics especially in transient state. So we confirmed that the surface kinetic model could play important roles in a useful tool for understanding detail reaction dynamics and searching the optimized operating conditions in the development of automotive catalysts which was always exposed to transient conditions. And the detailed reaction mechanisms in TWC and NSR catalyst were discussed on the basis of the calculated surface site coverage.

Air Quality Modeling Working Group developed two models to evaluate effects of automobile emission reduction measures on air quality improvement: Urban Air Quality Simulation Model in which secondary aerosol formation processes have been incorporated, and Roadside Air Quality Simulation Model in which micro-scale traffic flow has been taken into consideration. Concretely, a model has been built up for estimating SPM concentration in ambient air in which high concentrated air pollutants have been contained during summer and winter. The model has been built up by using UAM (Urban Airshed Model) as base model, and the following modification has been made to the base model. First, ISSOROPIA (secondary inorganic aerosol equilibrium model) has been added to the base model, and a secondary organic aerosol formation/reaction model (SOA model) has been incorporated into the model.

Comparing with the previous Auto/Oil programs, the total plan and current status of the air quality modeling study in JCAP are presented. The total plan of air quality modeling study has the following characteristics: 1) Vehicle emission inventory program is developed by considering the original features of Japan. 2) Not only the urban air quality but also the road sides pollutants dispersion is evaluated. 3) The chemical reaction model for the secondary particulate formations is developed on the basis of the smog chamber experiments. 4) For the cost-effectiveness analysis of vehicle/fuel technologies, the output of the air quality modeling will be combined with the cost data of new vehicle emission reduction technologies As the first step, preliminary modeling studies are conducted to understand the overall tendency of the air quality change toward 2010 in Tokyo urban area.

The emission characteristics of hydrocarbons during the cold start and the warm-up have been investigated. Timed sampling of hydrocarbon emissions upstream and downstream of a close-coupled catalytic converter have been carried out. The experimental results show that the emission characteristics of hydrocarbons are influenced by both the engine operating conditions and the heating characteristics of the catalytic converter. In the case of engine-out hydrocarbons, the total amount of hydrocarbons drastically decreases but the percentage contribution of the C2-C4 olefins to the engine-out hydrocarbons increases as the warm-up proceeds. Since these olefins have relatively high maximum incremental reactivity (MIR) factors, the specific reactivity (SR) of the engine-out hydrocarbons gradually increases during the warm-up. The adsorption and desorption processes of the engine-out hydrocarbons on the catalyst occur before the catalyst light-off.

The effects of fuel properties and emission control systems on exhaust hydrocarbon emissions have been studied. Using fourteen fuels with different properties, exhaust hydrocarbon emissions were measured for the two vehicle types with different emission control systems, under body catalyst and closed coupled catalyst, under the Federal Test Procedure. The fuel properties included high and low concentrations of olefins and aromatics as well as high and low T90. In addition, two fuels contained MTBE. The hydrocarbon emissions were discussed from the view point of the ozone reactivity and ozone formation potential. The results show that the high ozone reactivity of exhaust emissions are mainly caused by the olefins and aromatics in fuels. And also, the effects of fuel property change on exhaust emissions for the vehicle with an under body catalyst are more sensitive than the case of the vehicle with a closed coupled catalyst.