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A methodology for simulating effect of international variations in fuel compositions on spray combustion is proposed. The methodology is validated with spray combustion experiments with real fuels from three different countries. The compositions of those fuels were analyzed through GC×GC and H-NMR. It was found that ignition delay times, flame region and flame luminosity were significantly affected by the compositional variations. For the simulation, an evaporation surrogate consisting of twenty two species, covering basic molecular types and a wide range of carbon numbers, is developed. Each species in the evaporation surrogate is then virtually converted to a reaction surrogate consisting of n-hexadecane, methylcyclohexane and 1,2,4-trimethyl benzene so that combustion reactions can be calculated with a published kinetic model. The virtual species conversion (VSC) is made so as to take over combustion-related properties of each species of evaporation surrogates.

DiMethyl Ether (DME) has been known to be an outstanding fuel for combustion in diesel cycle engines for nearly twenty years. DME has a vapour pressure of approximately 0.5MPa at ambient temperature (293K), thus it requires pressurized fuel systems to keep it in liquid state which are similar to those for Liquefied Petroleum Gas (mixtures of propane and butane). The high vapour pressure of DME permits the possibility to optimize the fuel injection characteristic of direct injection diesel engines in order to achieve a fast evaporation and mixing with the charged gas in the combustion chamber, even at moderate fuel injection pressures. To understand the interrelation between the fuel flow inside the nozzle spray holes tests were carried out using 2D optically accessed nozzles coupled with modelling approaches for the fuel flow, cavitation, evaporation and the gas dynamics of 2-phase (liquid and gas) flows.

The effects of fuel injection timing on fuel-air mixture formation, combustion and emissions for a PREmixed lean DIesel Combustion (PREDIC) engine has been studied numerically by the KIVA II modeling package. The software was modified with an improved autoignition and combustion submodel, which describes the formation of combustible or ignitable fuel-air mixtures by turbulent mixing, and describes four chemical reactions, including low-temperature oxidation. The results indicate that the present computational model reproduces major features of two-stage autoignition and experimentally observed trends in NO and unburned fuel emissions. The relationships among in-cylinder distributions of fuel sprays, fuel-air equivalence ratio, temperature and mass fractions of NO and unburned fuel were demonstrated by graphically imaged results. A method of fuel-air mixture characterization has been introduced and used to analyze the numerical results.

Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some points of concern remained unsolved, such as a large increase in THC and CO, higher fuel consumption, and an operating region narrowly limited to partial loads, compared to conventional diesel operation. In this paper, the causes of PREDIC's problem areas were analyzed through engine performance tests and combustion observation with a single cylinder engine, through fuel spray observation with a high-pressure vessel, and through numerical modeling. Subsequently, measurable improvements were achieved on the basis of these analyses. As a result, the ignition and combustion processes were clarified in terms of PREDIC fuel-air mixture formation. Thus, THC and CO emissions could be decreased by adopting a pintle type injection nozzle, or a reduced top-land-crevice piston.

A study of the mixing mechanism of fuel with surrounding air is necessary in order to clarify the combustion process. In this study, the flow field near non-evaporating diesel spray as well as spray surface were observed and analyzed using a Nd-YAG laser light sheet. A single shot fuel spray was injected into a high pressure vessel and photographed under double-pulse laser illumination. The images of dispersed particles in the vessel were processed and velocity vectors were obtained by the auto-correlation method. Measured results showed temporal variation in the air movement around the spray. Just after the start of injection, air near the nozzle was pushed outward by the spray tip, after which the flow direction reversed. The air velocity ahead of spray tip was very low compared to fuel spray tip velocity. At a stable injection condition, air near the nozzle tip was pulled by the spray movement and flowed uniformly, and the spray-air boundary was smooth.

Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some problems still remain, such as higher fuel consumption, a lack of ignition timing control, and a large increase in THC and CO, compared to conventional diesel combustion. Appropriate mixture formation is necessary to solve these problems. In this paper, the influence of mixture formation on PREDIC was investigated. It was found that the pintle type injection nozzle was shown to be suitable for PREDIC, because it produced a comparatively uniform mixture in the combustion chamber and avoided collision of the fuel spray with the cylinder liner. Modeling by the KIVA-II software package was carried out to improve our understanding of the mixture formation process.