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It is well known that ethanol can be used in spark-ignition (SI) engines as a pure fuel or blended with gasoline. High enthalpy of vaporization of alcohols can affect air-fuel mixture formation prior to ignition and may form thicker liquid films around the intake valves, on the cylinder wall and piston crown. These liquid films can result in mixture non-homogeneities inside the combustion chamber and hence strongly influence the cyclic variability of early combustion stages. Starting from these considerations, the paper reports an experimental study of the initial phases of the combustion process in a single cylinder SI engine fueled with commercial gasoline and anhydrous ethanol, as well as their blend (50%vol alcohol). The engine was optically accessible and equipped with the cylinder head of a commercial power unit for two-wheel applications, with the same geometrical specifications (bore, stroke, compression ratio).

The role of Spark Ignition (SI) and Diesel engines as nanoparticles sources in urban area was investigated. Detection, sizing and counting of particles were realized at the exhaust of a Port Fuel Injection Spark Ignition (PFI SI) engine equipped with a Three-Way Catalyst (TWC) and a Unijet Common Rail (CR) Diesel engine equipped first with an Oxidation Catalyst (OC) and then with a Catalyzed Diesel Particulate Filter (CDPF). Engine operating conditions in high road traffic were considered. Electrical Low Pressure Impactor (ELPI) was used as real-time measurements device for particle size distribution in the range from 7 nm up to 10000 nm. Broadband UV-Visible Extinction and Scattering Spectroscopy (BUVESS) allowed investigating the chemical and physical nature of emitted particles. It was observed that the major contribution to particulate mass is due to Diesel engine equipped with the OC, the other engines contribute only in terms of number concentration.

Conventional methods for combustion gas concentration measurement are typically based on gas sampling, sample treatment and subsequent analysis. These procedures could affect the species concentrations in particular when temporal variations of process parameters are under study. Moreover, in these methods, the concentration measurements are usually performed at standard temperature and pressure. In order to overcome these limitations, in-situ and real-time concentration measurement techniques are needed. In this paper, an in-situ technique with high spatial and temporal resolution, based on ultraviolet-visible absorption spectroscopy, was proposed. This technique allowed the simultaneous determination of NO and OH absolute concentrations inside optically accessible diesel combustion chamber. Temporal and spatial distribution of OH and NO was evaluated.