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A unique time-resolved Fourier Transform InfraRed (FTIR) spectrometry technique has been developed to obtain full mid-IR lubricant spectra directly from the ring-pack region of a firing, single cylinder, diesel engine. Initial studies of the detailed spectra show a growth of oxidation products, as indicated by a strong carbonyl absorption peak, observed to increase with load close to the top ring location, for both power and exhaust strokes. Similarly, the formation of alcohol, ketone, aldehyde and carboxylate oxidation products is accessible. Thus it is possible to gauge gross changes to lubricant composition as a function of spatial location through the ring-pack, engine stroke and the severity of engine operation.

Departures from optimum stoichiometry during transients (acceleration and deceleration) and cold start can lead to significant degradation in driveability and emissions control. Such departures occur as a result of a complex interplay between fuel transport mechanisms and the fuelling strategy. The relative contributions of several of these mechanisms are affected by fuel composition. To help understand these effects an open-path differential infra-red absorption technique has been used to monitor the transient evolution of the fuel vapour phase directly within the combustion chamber. The sensor projected a narrow infra-red beam which traversed the cylinder of an optical access engine along an open path under the head, and measured the path-integrated attenuation caused by absorption of the infra-red radiation by the fuel vapour. It operated in the near infrared (NIR) spectral region around 2.3 μm, an absorption band in hydrocarbon species containing methyl groups.

Mid-infrared reflection-absorption spectroscopy, has been applied for the first time to the measurement of lubricant degradation products in the ring pack of a firing single-cylinder, IDI diesel. An IR-transmitting window, mounted in the cylinder wall, enables illumination of the moving piston by a broadband IR source located on the engine exterior. Light reflected from the piston is analysed in three wavebands to measure carbonyl oxidation products and oil volumes. Intra-cycle observations reveal differences in the apparent extent of lubricant oxidation between strokes and at different spatial locations in the ring pack. The data are interpreted in terms of a non-homogeneous sample.