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An experiment was conducted with a direct injection Diesel engine operated with neat dimethyl ether (DME). Main focus of this research is to investigate the performance of the catalysts designed for NOx reduction, such as Co–alumina and Sn–alumina catalysts, for the reduction of NOX and other unburned species contained in the exhaust gas. In the experiments, DME concentration in the exhaust gas was changed by adding extra DME before the catalytic reactor, which is the important experimental parameter in the research. Results showed that NOX reduction rate was not so high without any DME addition, because the content of unburned DME, reducing agent, is very low in the DME engine exhaust gas. However, NOX reduction rate increased with increase in DME content and it reached around 80% with enough DME addition. The NOX reduction rate increased with increase in reaction temperature up to around 300 °C.

A novel way of using low-cetane-number petroleum gases in a compression ignition (CI) engine is introduced, by directly injecting blends of such fuels with dimethyl ether (DME), a high-cetane-number alternative fuel for low soot emissions. This method both extends advantages of DME and complements its deficiency. Although DME mixes with most hydrocarbon fuels in any ratio, in order to demonstrate the feasibility of the new method and facilitate the analysis, DME-propane blends were investigated in a direct injection CI engine. Some findings of the study are listed. In the engine operated by DME and propane blends, there was no need for significantly increasing the complexity of the fuel system than that employed in the use of neat DME. For the same reason, this method eliminates or minimizes cumbersome hardware necessary when the said gaseous fuels are separately introduced in CI engines.

Neat dimethyl ether (DME), as an alternative fuel candidate for Diesel engines, was investigated by measuring primarily engine performance and exhaust gas characteristics. In addition, other responses of the engine to the new fuel were also determined at the same time, including the injector needle lift and heat release. The engine measurements with this fuel were compared with those obtained by using conventional Diesel fuel. Findings from the present work include: (1) It was necessary to add a small amount of lubricating additives to DME, if a conventional fuel injection system is employed.

The combustion in a spark ignition engine was studied when it was fueled by neat methanol using the timed injection method at the intake port. The measurements from this fueling were compared with those obtained from a carburetor fueled operation. In the study, results of the cylinder pressure analysis and the in-cylinder high-speed photographic observation showed that the reaction in the timed methanol engine combustion had multiple-stage combustion processes. The multiple-stage reaction was pronounced based on the double spikes in heat release history and droplets individually burning in the mixture. The injection time for the best methanol fueled engine operation seemed to be that right after the intake valve opening when the lowest specific fuel consumption was obtained with smallest cyclic variation in the pressure-time history and when the lowest emissions (NOx, UHC and HCHO) were produced.

Engine combustion behaviors were investigated when the mixture condition at the intake port was varied. This experimental study was performed for several engine variables including types of cylinder head (gas motions), spark plug loction and MBT timing. Among the variables for the mixture condition at induction were the fuel/air mixture ratio (excess air factor) and the portion of atomized liquid fuel out of total fuel in the mixture. The engine operation was analyzed by obtaining the mean effective pressure, thermal efficiency, heat release history, stability of combustion, and lean misfire limit.