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The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

The real-time concentrations of benzene, toluene, xylene, trimethyl-benzene and naphthalene in vehicle exhaust have been monitored during the FTP-cycle with a time-resolution of 20 ms and a sensitivity of 50 ppb. Using a laser mass spectrometer, the aromatic hydrocarbons in unconditioned exhaust gas at sampling positions behind the exhaust valve, before and behind the catalytic converter have been analyzed. The comparison of the emissions sampled before and behind the catalytic converter reveals the effect of dealkylation of the aromatic hydrocarbons in the catalytic converter. Whereas most of the aromatic hydrocarbons are burned in the hot catalytic converter, however, bursts of aromatic hydrocarbons are released at transient motor operation. In these moments, which can be attributed to phases of closed throttle valve and very low engine load at gear changes, a significant part of the C1-, C2- and C3- benzenes has been converted into benzene.