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The oxidation of surrogate diesel fuels composed of mixtures of three pure hydrocarbons with and without their cetane numbers chemically enhanced using 2-ethylhexyl nitrate (2-EHN) is studied in a variable pressure flow reactor over a temperature range 500 - 900 K, at 12.5 atmospheres and a fixed reaction time of 1.8 sec. Changes in both low temperature, intermediate temperature, and hot ignition chemical kinetic behavior are noted with changes in the fuel cetane number. Differences appear in the product distribution and in heat release generated in the low and intermediate temperature regimes as cetane number is increased. A chemically enhanced cetane fuel shows nearly identical oxidation characteristics to those obtained using pure fuel blends to produce the enhanced cetane value. The decomposition chemistry of 2-EHN was also studied. Pyrolysis data of 10% 2-EHN in n-heptane and toluene are reported.

A mini-dilution tube to measure particulate emissions is described and results obtained in an application are presented. The application selected is a study of fuel effects on stratified charge engine emission and combustion characteristics. The mini-dilution tube was developed to provide a capability for particulate measurements with dynamometer engines. The device has been demonstrated to yield particulate mass results agreeing to within 10 percent of those with a full scale tunnel in steady state tests with diesel powered vehicles. A PROCO engine modified by incorporation of Torch Ignition was used in the study. Fuels were a wide cut gasoline, methanol and Indolene Clear gasoline. The engine was operated at a speed of 1250 rpm with an indicated mean effective pressure of 390 kPa. Spark timing, injection timing, EGR and equivalence ratio were varied.