The Influence of Solid Anisotropy on Flame Spread over Melting Polymers 2014-01-0429

Flame spread over a melting thermally thick composite polymer is investigated in a channel flow above a condensed fuel. The condensed fuel consists of an isotropic (melted layer of) liquid near the heated surface and an anisotropic (not-yet-melted) solid surrounding it. The influence of the solid anisotropy is evaluated by changing the solid conductivity (k_sx or k_sy) in one particular direction (x in horizontal flame spread direction or y in vertical direction, see schematics in Figure 1) while keeping the other properties fixed. Note that the liquid conductivity k_l has no isotropic behavior. Numerically, it is found that the flame spread rate decreases with either increasing k_sx or k_sy. The decrease with respect to k_sy is less than for a comparable case described by the de Ris formula for an isotropic pure solid. The flame spread rate is more accurately determined by an analytical formula derived for spread across a melting solid fuel. Qualitatively, the liquid layer extent decreases with either increasing k_sx or k_sy due to the role played by the solid conduction as a heat loss mechanism in a thermally thick fuel. In addition, k_sy more strongly influences the extent of the liquid layer than k_sx in that it changes both the horizontal and vertical boundaries of the liquid layer. The surface parameters and energy balance show the dependence of the flame size on k_sx and k_sy. Generally, the size of the spreading flame decreases with either increasing k_sx or k_sy. The influence of the condensed phase anisotropy is also studied by the influence of other overall quantities such as the heat flux region, the mass flux region, and the ignition delay.