Scavenger free three-way catalyst with low hydrogen sulfide emission 2000-05-0308

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide. It is found that the new type catalysts including the composite cerium oxide show low H₂S emission without activity loss even after high temperature lean aging treatment.