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Acoustics, in a broad sense, is an essential product attribute in the automotive industry, therefore, it is relevant to study and compare theoretical and numerical predictions to experimental acoustic measurements, key elements of many acoustic development processes. The numerical methods used in the industry for acoustic predictions are widely used for exhaust system optimization. However, the numerical and theoretical predictions very often differ from experimental results, due to modeling simplifications, temperature variations (which have high influence on speed of sound), manufacturing variations in prototype parts among others. This article aims to demonstrate the relevant steps for acoustics development applied in automotive exhaust systems and present a comparative study between experimental tests and computer simulations results for each process. The exhaust system chosen for this development was intended for a popular car 4-cylinder 1.0-liter engine.