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Physicochemical characteristics of particulate matters which are influenced by engine oil additives from engine combustion of diesel and synthetic biodiesel: hydrotreated vegetable oil (HVO) were successfully investigated using electron microscopy, electron dispersive x-ray spectroscopy and thermogravimetric analysis. The agglomerate structure of diesel PM, HVO PM and diesel blending lubricant PM are similar in micro-scales. However, nanostructure of soot is a spherical shape composed of curve line crystallites while the metal oxide ash nanostructure is composed of parallel straight line hatch patterns. The oxidation kinetics of fuel blending lubricant PMs are higher than neat fuel PMs due to catalytic effect of incombustible metal additives from engine lubricating oil.

The exhaust emissions from diesel combustion are the sources of particulate matter emitted to the atmosphere, which are components of air pollution that implicated in human health such as lung cancer. At present the diesel particulate filter can remove PM from the exhaust gas before emitted to the atmosphere. This research is investigating morphology and structure of acicular mullite to develop the fabrication process filter in order to study particulate matters trapping and oxidation mechanisms. This paper used two main substances to study the structure of diesel particulate filter (DPFs); Aluminum oxide (Al2O3) and Silicon dioxide (SiO2). These are mainly in the conventional DPFs. The variable substances are Titanium dioxide (TiO2) and Vanadium oxide (V2O5), which added to investigate and produce the acicular mullite DPFs structure. The mullite samples were sintered at 1300 oC with holding time of 1 h.

Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.

Derived from palm Fatty Acid Methyl Ester (FAME), high quality biodiesel called H-FAME has been introduced in order to increase its percentage blended with diesel. Due to monoenen-rich FAME by partial hydrogenation process, H-FAME is superior oxidation and thermal stability. In the current study, the effects of 20 percent of high quality biodiesel blended with diesel (B20) on the compatibility of polymeric engine parts have been investigated by means of the immersion test. Pure diesel has also test as the reference. Following SAE J1748 in conjunction with ASTM D471, selected commercial engine parts such as fuel hose and tank were immersed in the test fuels. In addition, Viton fluoroelastomers, neoprene and nitrile butadiene rubber (NBR) were also soaked for comparison. Apparent percent weight increase was used to indicate the change of the engine parts after exposed to the test fuels. Mechanical properties, tensile test was performed to manifest the compatibility of elastomers.

Nowadays, the diesel engine models are developed from a unit pump to a common-rail injector. With palm methyl ester (commonly known as biodiesel) with higher viscosity and density than conventional diesel being used as alternative fuel for diesel, palm methyl ester may affect the injection characteristics. Injection pressure is one of the important parameters of common rail injector. Because of its effects on the pressure between command port and control volume, which activates a needle lift during injection process. This paper presents injection characteristics of solenoid injector experimented in a Zeuch’s chamber with a focus on injection pressure frequency, injection pressure amplitude, injection pressure stable duration. Commercial diesel (with mandate of 5% biodiesel blend or B5) and palm methyl ester (B100) were used as the test fuels at various injection pressures (40, 80, 120 and 160 MPa).

As well-known, the diesel engine has the highest thermal efficiency at the same load as compared with internal combustion engine but its disadvantage is particulate matter (PM) emitted to the atmosphere. The studies of this paper were divided into two parts. The first part studied the quantity of PM from the both diesel and biodiesel fuels at 80% load (2400 rpm) by the trapping process on diesel particulate filter (DPF) used in a partial flow dilution tunnel. The second part studied the regeneration process of PM under the flow rate of oxygen and nitrogen gas of 13.5 L/min with 10%, 15%, and 21% of oxygen gas. The result showed that amount of PM from biodiesel fuel was lower around two times than PM from diesel fuel. The duration in regeneration process of biodiesel's PM was shorter than diesel while increasing of oxygen percentage can reduce regeneration time.

The purpose of this study is to investigate the effects of injection timing and injection pressure on combustion characteristics and emissions of the direct injection single cylinder CI engine fueled with ethanol ED95 fuel (95% hydrous ethanol blended with 5% commercial additive by volume) under partially premixed combustion condition. The engine was modified to increase the compression ratio from 18 to 28. The experiment was tested at maximum engine load under a constant engine speed for all testing conditions. The experimental results show a lower coefficient of variation (COV) for the indicated mean effective pressure (IMEP), which implies that higher combustion stability is achieved when the injection timing is advanced. However, the ignition delay significantly increases. In addition, when injection timing is advanced and the injection pressure is increased, THC and CO emissions increase due to lower combustion efficiency.

The effects of high quality biodiesel, namely, partially Hydrogenated Fatty Acid Methyl Ester or H-FAME, on 50,000km on-road durability test of unmodified common-rail vehicle have been investigated. Thailand popular brand new common-rail light duty vehicle, Isuzu D-Max Spacecab, equipped with 4JK1-STD engine (DOHC 4-cylinder 2.5L, M/T 4×2, Euro III emission) was chosen to undergo on-road test composed of well-mixed types of mountain, suburb and urban road conditions over the entire 50,000km. Jatropha-derived high quality biodiesel, H-FAME, conforming to WWFC (worldwide fuel charter) specification, was blended with normal diesel (Euro IV) at 10% (v/v) as tested fuel. Engine performance (torque and power), emission (CO, NOx, HC+NOx and PM), fuel consumption and dynamic response (0-100km acceleration time and maximum velocity) were analyzed at initial, middle and final distance; whereas, used lube oil analysis was conducted every 10,000km.

Formerly, the Hydro-treated Vegetable Oil (HVO) blended fuels has been studied by running the New European Driving Cycle (NEDC) and found that the higher HVO blended fuel can suppress NOX, lowering the particulate matter (PM) while improving the vehicle fuel economy. The result also shown that the 20% HVO + 5%FAME blended with diesel fuel has been proven to compatible with the advance diesel engine technology via the severe engine durability tests and fuel injection system tests. Therefore, the effects of two paraffinic diesel fuels, which are Gas-to-Liquid (GTL) and Hydro-treated Vegetable Oil (HVO), on a common-rail DI diesel engine have been mainly focused in this work. The main objective of this work was to study the relationships between fuel properties and theirs combustion characteristics by analyzing cylinder pressure data and exhaust emissions intensively.

The increase of air pollution and global warming is a threat for human life. Besides, the price of petroleum is increasing rapidly and the resources are diminishing. This obliged scientists and engineers to look for alternative sources of energy, which are cleaner and more sustainable. Biodiesel, defined as mono-alkyls of esters from vegetable oils and animals fat, is a cleaner renewable fuel and has been considered as the best alternative for petroleum based diesel fuel hence it can be used in any compression ignition engines without any significant modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions due to their higher content of oxygen. The produce less soot and hence the feed stuck is plant it will regenerate the CO2 by the photosynthesis which ensures the renewability and reduces global warming.

Nanostructures of diesel and biodiesel engine particulate matters (PMs) were investigated by using a Transmission Electron Microscopy (TEM). The average single particle sizes of biodiesel and diesel PMs are approximately 30-40 nm and 50-60 nm, respectively. Image processing process was used to estimate each carbon platelet length by using TEM image. The average carbon platelet length of biodiesel and diesel PMs are in the range of 0.1-7.0 nm. Moreover, carbon atoms per cubic volume of PMs are approximately 500-900. The result shows that engine load and fuel property are strongly impact on the size of single particle and carbon atom density of particle. This is one of interesting behaviors need to be investigated for better understanding. The results of this research would be used as basic information for design and develop removing process of PM emitted from engine combustion which using in diesel and biodiesel fuels.

The objective of the present research is to investigate the effects on diesel engine combustion and NOx and PM emission characteristics in case of blending the ordinary diesel fuel with biodiesel in passenger car diesel engines. Firstly, we conducted experiments to identify the combustion and emissions characteristics in a modern diesel engine complying with the EURO 4 emission standard. Then, we developed a numerical simulation model to explain and generalize biodiesel combustion phenomena in detail and generalize emission characteristics. The experimental and simulation results are useful to reduce biodiesel emissions by controlling engine operating and design parameters in the diesel engine. Engine tests were conducted and a mathematical model created to investigate the effects of 40% and 100% methyl oleate modeled fuel representing Jatropha-derived biodiesel on diesel combustion and emission characteristics, over a wide range of passenger car DI diesel engine operating conditions.

The increasing of global energy demand and stringent pollution regulations have promoted research on alternative fuels. In Thailand, ethanol, can be produced from many sources of national agriculture products as renewable fuel, which was strongly promoted by government due to its many merits for use in transportation field. In this study, combustion characteristics of ethanol-gasoline blend (20%, 85%, and 100%) as well as pure gasoline (E0) were investigated by using a swirl-generated constant volume combustion chamber. Flame propagations of different fuel blends were observed by high speed Schlieren photography technique while pressure history data were recorded for detailed combustion analysis. Combustion behavior, combustion duration and rate of pressure rise of all tested fuels were investigated in various swirl intensities and equivalence ratios. In addition, effect of swirl intensities and ethanol concentration on lean misfire limit were also discussed.

The present study aims to investigate the parameters affecting cold start characteristics of ethanol at low temperature, and suggest a solution to avoid cold starting problem without the installation of second fuel tank. The testing engine is a 125cc volume displacement, single-cylinder four strokes SI engine with fuel injection and ignition timing system controlled by ECU (electronic control unit). The cold starting performance tests were extensively conducted with different percentages of ethanol blends, surrounding temperatures, heating inside combustion chamber, heater injector, pre-cranking without fuel injection, and amount of fuel injection. From the experimental results, when using ethanol fuel in conventional engine, the problem of cold starting was observed at surrounding temperature lower than 20°C for ethanol. Increasing of injection duration can lower the possible cold start temperature of neat ethanol.