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Nitrous oxide (N2O) is a strong green house effect gas and three-way catalyst is one of the major sources. N2O is mostly emitted at temperatures during the process of light off in the catalyst and the frequency of this temperature range over total temperature range distribution affects strongly on N2O emission. The effect of cold ambient on N2O emission was analyzed based on N2O-catalyst temperature characteristics and catalyst temperature data gained by road driving test at north part of Japan in winter. As results, N2O emission may drastically increase in colder cities and winter city traffic conditions.

To derive an effective technique for reducing a greenhouse gas nitrous oxide (N2O) emitted from automobiles, we prepared experimental three-way catalysts carrying various types and quantities of precious metals, and investigated their N2O generation and conversion characteristics. In view of previous reports on increased N2O emissions from in-use automobiles, we deactivated the catalysts in a rapid aging test, and observed the effect of catalyst deactivation on N2O generation and conversion by the catalysts. We found that the concentrations of generated N2O decreased as the quantities of precious metals carried by catalysts were decreased and that, accordingly, these low-carrying catalysts are more advantageous from the standpoint of reducing N2O generation. However, the concentrations of generated N2O increased as the catalysts were deactivated.

As a method for reducing exhaust emissions from diesel engines, we have experimented on a homogeneous charge diesel combustion technique (HCDC) whereby a portion of fuel is supplied into the intake port to form a homogeneous premixture, this is then fed into the cylinder from the intake port before ignition of the diesel fuel, which is injected directly into the cylinder. Our results have indicated possibilities of substantially reducing both NOx and smoke emissions. If diesel fuel is premixed with air, the premixture under-goes excessively early self-ignition, making it difficult to maintain ignition timing near top dead center and hence limiting the engine operating conditions. While an important target in emission reduction is to realize stable low-emission combustion during a high-load operation, the actual operation of diesel engines mostly involves partial-load conditions.

The objective of this study is to improve fuel economy and reduce carbon dioxide emissions in diesel-electric hybrid automotive powertrains by developing an exhaust gas turbine generator system which utilizes exhaust gas energy from the turbocharger waste gate. The design of the exhaust gas turbine generator was based on a conventional turbocharger for a direct-injection diesel engine. Data from steady-state bench tests using air indicates about 50% of the turbine input energy can be converted to electric energy. Turbine generator output averaged 3 kW, while a maximum of about 6 kW was observed. Based on this data, we estimate that energy consumption in a vehicle could be reduced between 5% and 10%. Engine tests were conducted under both steady-state and transient conditions. These tests revealed that optimal performance occurred under high-speed, high-load conditions, typical of highway or uphill driving, and that performance at low-speed, low-loads was relatively poor.

Under heavy load condition, single fuel operation with diesel fuel was studied experimentally for the homogeneous charge diesel combustion (HCDC) method. HCDC engine, in which pre-mixture was formed by fuel injected into an intake manifold and mixed with air beforehand then ignited by small amount of fuel directly injected into a cylinder, can reduce NOx and smoke simultaneously from the diesel engine. In HCDC the higher the premixed fuel ratio was, the lower the emissions were. Accordingly, it was indicated that homogeneous pre-mixture contributed to improvement of exhaust emissions. However, a diesel knocking due to uncontrolled self-ignition may occur under high premixed fuel ratio conditions in the case of operating heavy loads. Thus, the maximum amount of premixed fuel was restricted by these knocking limits.

To find a clue to reduction techniques for Nitrous Oxide (N2O) emission from three-way catalyst equipped vehicles, four test samples of three-way catalysts with typical noble metal compositions were fabricated by way of experiment and their N2O formation characteristics have been experimentally studied. Then, these catalyst samples were conditioned artificially by aging with real automotive exhaust gas and the N2O formation characteristics after aging has been also observed. As results, catalyst temperature zones and concentration levels of N2O formation varies greatly by the catalyst composition. In general, a catalyst with lower metal content showed lower N2O mass emission at both fresh and after aging conditions. The tendency of the increase in N2O mass emission due to the deterioration is also different among the tested catalyst samples.

A homogeneous Charge Compression Ignition Diesel Combustion (HCDC) system has been experimentally studied for it's effect on exhaust purification of diesel engines. In this system, most fuel is injected into the intake manifold to form homogeneous pre-mixture in the combustion chamber beforehand and the pre-mixture is ignited with a small amount of fuel directly injected into the cylinder by a conventional injection system. Because this system performs homogeneous lean-burn, it can realize low emission which cannot be realized by conventional diesel engines without impairing ignition controllability in the operations ranging from idle to full load. In particular, although the operating regions were strictly limited, extremely low Nox emission levels of as low as 10 to 40 ppm were realized with maintaining low smoke emissions, when the ratio of pre-mixed fuel was increased up to approx. 98%.

An experimental and a numerical analysis wereconducted based on the concept of homogeneous charge diesel combustion (HCDC), in which most of the fuel is supplied for pre-mixed homogeneous charge which is compressed in the cylinder and then ignited by small amount of diesel fuel directly injected into a cylinder. At the previous report, It was indicated that simultaneous improvement of NOx and smoke were possible. Especially under a certain condition, NOx was extremely reduced. This report describes the preliminary analysis for the cause of this emission improvement with HCDC method. As result, direct optical observation of the combustion phenomena and numerical analysis using KIVA2 code suggested that low NOx combustion may be caused by lowered combustion temperature and reduced combustion period due to the uniform lean combustion.

Exhaust gases discharged from automobiles are noticed as one of the reasons for resent increase in atmospheric methane (CH4) and nitrous oxide (N2O) concentration, which have been considered as greenhouse effect gas. In order to make an accurate estimation of methane and nitrous oxide discharged from automobiles, measurement methods of them were experimentally developed and their emissions were measured for different kinds of automobiles under various driving conditions. Then, we have tried to estimate the annual global emissions from automobiles using these measurement results and statistical data such as the number of automobiles, the total annual mileage, and the total annual fuel consumption etc. As results, their emissions from passenger vehicles which have been estimated from global number of automobiles were 477.263 t/year for methane and 313.472 t/year for nitrous oxide. These numbers are higher than what had been estimated.

An attempt was made to optimize NOx and particulate emissions from heavy-duty diesel powered vehicles under heavy load engine operating regions by combining EGR and methanol fumigation and the effects on exhaust emissions were experimentally studied. The results under steady states tests show that, the smoke concentration is decreased and total fuel consumption is improved according to the increase in methanol energy ratio. As NOx reduction effect of EGR does not affected by methanol fumigation, drastic NOx reduction can be thereby possible at heavy load regions with the combined use of EGR and methanol fumigation. Then, this method was applied to new Japanese 13 mode test procedure and it was recognized that the NOx mass emissions were reduced to almost one half without increase in particulate emissions. However, drastic increase in CO, HC and aldehyde emissions were observed also.

Combined system with EGR and Manifold water injection was developed for trial to control exhaust NOx emissions from heavy-duty diesel powered vehicles and its effects were experimentally studied under not only steady-state but also actual driving conditions including transient. From the experimental analyses under steady-state conditions, it was recognized that higher NOx reduction may be possible with this combined system compared with the use of each method alone under the same level of other pollutants. Then, several control conditions of the system were chosen and their effects to exhaust emissions were investigated under actual driving conditions, and consequently, about 50% of NOx reduction was recognized without significant increase of other pollutants by the combination of EGR at light and medium load regions and limited water injection at heavy load regions where accelerator opening is 70% or over.

Experiments and analyses were carried out to determine the effects of EGR on NOx and other pollutants for heavy-duty direct injection diesel engines under steady state conditions. Then based on them, optimum EGR control method was examined for effective NOx reduction without causing substantial increases of other pollutants under transient conditions. A simple EGR control system was developed for trial to achieve almost the same effects of the said method. Results of experiments with this system indicated that the EGR control method was capable of substantial reduction of NOx mass emission during transient engine operations equivalent to actual driving conditions, with different pay-loads and average vehicle speeds. REDUCTION of the NOx mass emission from heavy-duty diesel powered vehicles during actual driving operations, is one of the most important demands in automobile technologies.