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A method was studied for simultaneous zinc phosphating on aluminum and steel surfaces to obtain high corrosion resistance on aluminum surfaces, which conventional phosphatic processing could not provide with sufficient corrosion resistance. Since aluminum is protected by an oxide film on its surface, it has poor processability with zinc phosphating solutions applied to steel. An appropriate quantity of fluoride was therefore added to improve processing, and the coating film, aluminum composition and surface conditions were optimized to suppress filiform corrosion, which is characterized by string-like blisters of paint film starting from a paint defect. In addition, in view of the actual production environment, the corrosion resistance of the ground area made for readjustment after stamping was studied for the optimization of the processing solution.

In order to investigate the corrosion resistance of organic composite-coated steel sheets ( OCS ) in a real automotive environment, many kinds of corrosion tests were performed on test pieces and real automotive doors. Tests with a corrosive solution including iron rust were introduced to simulate the real corrosive environment of automotive doors. The relationship between the components of OCS and the corrosion resistance in the rust-including tests was examined. In addition, electrochemical studies were performed. Results indicate OCS has much better corrosion resistance than plated steel sheets with heavier coating weight in all tests. OCS shows excellent corrosion resistance in rust-free corrosive solution, however, some types of OCS do have corrosion concerns in rust-including tests. It became clear that these OCS types have an organic coating with lower cross-linking.