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A zirconia electroysis cell is an all-solid state (mainly ceramic) device consisting of two electrodes separated by a dense zirconia electrolyte. The cell electrochemically reduces carbon dioxide to oxygen and carbon monoxide at elevated temperatures (800 to 1000°C). The zirconia electrolysis cell provides a simple, lightweight, low-volume system for Mars In-Situ Resource Utilization (ISRU) applications. This paper describes the fabrication process and discusses the electrochemical performance and other properties of zirconia electrolysis cells made by the tape calendering method. Electrolytes produced by this method are very thin (micrometer-thick); the thin electrolyte reduces ohmic losses in the cell, permitting efficient operation at temperatures of 800°C or below.

In-situ production of oxygen and methane for utilization as a return propellant from Mars for both sample-return and manned missions is currently being developed by NASA in cooperation with major aerospace companies. Various technologies are being evaluated using computer modeling and analysis at the system level. An integrated system that processes the carbon dioxide in the Mars atmosphere to produce liquid propellants has been analyzed. The system is based on the Sabatier reaction that utilizes carbon dioxide and hydrogen to produce methane and water. The water is then electrolyzed to produce hydrogen and oxygen. While the hydrogen is recycled, the propellant gases are liquefied and stored for later use. The process model considers the surface conditions on Mars (temperature, pressure, composition), energy usage, and thermal integration effects on the overall system weight and size. Current mission scenarios require a system that will produce 0.7 kg of propellant a day for 500 days.

Biological wastewater processing has been under investigation by AlliedSignal Aerospace and NASA Johnson Space Center (JSC) for future use in space. Testing at JSC in the Hybrid Regenerative Water Recovery System (HRWRS) in preparation for future closed human testing has been performed. Computer models have been developed to aid in the design of a new four-person immobilized cell bioreactor. The design of the reactor and validation of the computer model is presented. In addition, the total organic carbon (TOC) computer model has been expanded to begin investigation of nitrification. This model is being developed to identify the key parameters of the nitrification process, and to improve the design and operating conditions of nitrifying bioreactors. In addition, the model can be used as a design tool to rapidly predict the effects of changes in operational conditions and reactor design, significantly reducing the number and duration of experiments required.