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In Brazil, the introduction of high biodiesel blends has been defined by standard CNPE no 16 of 2018, which stablished the latest chronogram for compulsory biodiesel incorporation to all diesel fuel commercialized nationally, from 11% v/v in 2019 to 15% v/v in 2023, and up to B20 in case of captive fleets. Nevertheless, with the adoption of more stringent emission standards in Brazil, concerns arise from the unrestricted use of higher biodiesel blends, especially regarding the assurance of Heavy-Duty Diesel (HDD) emissions aftertreatment systems correct operation and of fulfillment of national emissions requirements defined by PROCONVE. Considering the current emission standards (PROCONVE P7, equivalent to EURO V), such concerns already take place and become critical with the perspective of PROCONVE P8 (EURO VI) implementation, in 2022 for new models and 2023 for all commercialized vehicles, as defined by CONAMA Resolution no 490/2018.

Vehicles manufacturers, in search of cost reduction, fill the tanks of recently manufactured vehicles with the least volume of fuel necessary for future commercialization. The adoption of such practice, depending on the diesel fuel storage conditions, may lead to oxidation products formation in the fuel system and to problems during the first start of these vehicles. Some vehicles manufacturers, trying to minimize the occurrence of these problems, replace the diesel fuel in the vehicle tank with new fuel when vehicle storage time reaches 90 days. As a result of such occurrences, the opportunity for a first fill diesel fuel development, that presented better oxidation stability during storage, was identified. In the first stage of the special diesel fuel development, various analyses where conducted in laboratory, in the sense of defining criteria for the fuel formulation, taking into consideration the chemical variability of commercial Brazilian diesel fuel type A and biodiesel.

Over the last few years the continuous air quality improvements to minimize the amount of toxical and harmful exhaust gases from diesel-powered vehicles has led to stricter diesel fuel specifications. The sulfur reduction in diesel fuel has resulted in poor fuel lubricity on account of deep hydrotreating that also reduces most polar compounds that provide natural lubricity. In this paper, we verify the diesel fuel composition effect on fuel lubricity, monitored by HFRR method. The variables used included sulfur and nitrogen compounds, aromatics compounds, density, viscosity, and so on. This study also involved a statistical analysis of an eighteen-fuel matrix.