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The diesel oxidation catalysts (DOC) having high purification performance to the exhaust gas at low temperatures were investigated. In this paper two main technological improvements from conventional DOC are shown. First is forming Pt/Pd composite particles in order to suppress sintering of precious metal under high thermal aging condition. This generating Pt/Pd composite and the effect were exemplified by TEM-EDS and XRD analysis. Second is adjusting electric charge of Pt/Pd surface to reduce interaction between Pt/Pd and carbon monoxide (CO) by modifying the support material components. Adjusting electric charge of Pt/Pd surface by applying new support material could cancel CO poisoning at Pt/Pd surface. Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) studies suggested that improved support material is more suitable for CO oxidation at a low temperature based on the concept.

In this study several NOx storage materials have been investigated to see their NOx storage properties. And sulfur release properties of these materials have been also investigated. Based on these findings, new LNT catalyst was developed. In this new LNT catalyst Barium is supported on one basic material, and Strontium is coated in the whole catalyst with high dispersion. And it shows higher NOx storage performance against conventional LNT one even though 10g/L of sulfur was introduced to the catalysts. According to analysis results of new LNT catalyst after sulfur poisoning, it was found that sulfur was mainly adsorbed on Strontium selectively, and then it formed sulfate compound as SrSO4. On the other hand, another sulfate compounds could be hardly observed. And regarding Barium on basic material some analysis measurement said that it has not only better NOx storage function, but also better sulfur release function.

For fuel economy improvement by lean-burn gasoline engines, extension of their lean operation range to higher loads is desirable as more fuel is consumed during acceleration. Urgently needed therefore is development of emission control systems having as high NOx conversion efficiency as three-way catalysts (TWC) even with more frequent lean operation. The authors conducted a study using catalysts loaded with potassium (K) as the only NOx trapping agent in an emission control system of a lean-burn gasoline engine.

The control over particulate emissions is becoming increasingly important in modern diesel engines for Heavy Duty applications, that will comply to more and more stringent emissions norms. Use of particulate traps is an effective means of achieving this with the need to regenerate the particulate trap being imperative. Passive regeneration using NO2 by conversion of NO, as well as regeneration at lower temperatures with catalyzed DPF and the influence of NOx to soot ratio on this, is the subject of the paper. Both coated and uncoated filters in fresh and aged state are evaluated at temperatures typical of passive NO2 and Oxygen-based soot regenerations and the results discussed.

Particulate filters are currently the method of choice for reducing soot levels in diesel exhaust to the extremely low levels required for meeting future emission standards. For cost effective, reliable and manageable soot regeneration, the Catalytic Diesel Particulate Filter (CDPF) has proven to be one of the most promising solutions for maintaining filter performance. The activity of the CDPF can help lower soot ignition temperature thereby promoting active, oxygen-based filter regeneration. It can also facilitate passive regeneration of a filter at temperatures below 400 °C through formation of NO2 by catalyzing the oxidation of NO. There are two important factors which affect the passive regeneration of a CDPF. One is the influence of NOX/soot ratio. The other is the deterioration of the catalytic function upon aging. Together they determine the quantity of NO2 available for soot oxidation.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

Practical application of leanburn gasoline engines for passenger cars has been increasing in recent years. The leanburn gasoline engine is operated under high air fuel (A/F) ratio to improve fuel economy. However, reduction of NOx from the exhaust under oxygen-rich condition is very difficult to achieve. The Three Way Catalyst (TWC) designed for conventional gasoline engines cannot be applied to the leanburn gasoline engine because of low NOx conversion under lean conditions. To achieve better fuel economy and lower emissions, a breakthrough in NOx control technology for oxygen-rich conditions is needed. To address this need, a new type of catalyst technology using Iridium was developed. This new catalyst can constantly reduce NOx from exhaust under lean conditions using hydrocarbons as reducing agents. This is accomplished without formation of N2O. In addition, the newly developed catalyst has a tolerance for sulfur poisoning and exhibits reasonable heat stability.