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A new fast response NO detector, based on the chemiluminescence (CLD) method has been used to measure continuous, real time levels of NO in the cylinder, and simultaneously in the exhaust port of a virtually unmodified production SI engine. The real time NO concentration data show a great deal of information. Simultaneous NO measurements taken in-cylinder at sample points a few millimetres apart show substantial differences. Exhaust and in-cylinder levels from the same cycle show even greater differences, though the levels on average are well correlated.

A novel Fast Response Chemiluminescence Detector and a Fast Flame Ionization detector have been used to examine the instantaneous NO and unburnt hydrocarbon concentration in the cylinder and exhaust port of a DI Diesel engine. The in-cylinder results indicate very high levels of NO in the premixed phase of combustion, followed by generally lower levels during the diffusion burning phase. Hydrocarbon signals also indicate significant detail. The in-cylinder uHC signal is consistent with the probe location being between two of the fuel sprays. Both in-cylinder and exhaust results indicate rather high cyclic variability in the NO levels at steady conditions. Variations in the timing and structure of the exhaust uHC signal during the valve open period with load may give insight into the fuel spray/air motion.

For domestically produced passenger car gasoline fuelled vehicles, the forthcoming task of emissions compliance in India (Bharat-IV by 2010) may require a more detailed knowledge of transient engine behaviour by Indian engineers. Under steady state conditions and with reasonable fuel preparation, three-way catalytic converters can remove around 98% of legislated pollutants. However, during cold start and gear changes, the transient emissions are not fully converted by the catalyst; the cold start alone contributing typically 90% of the total Cycle Hydrocarbon (HC) emissions for the Euro- IV drive cycle [1]. This paper presents data measured pre and post the three-way catalyst on a EURO- III compliant European manufactured production Port-Fuel-Injection (PFI) gasoline engine running on a FTP drive cycle. The transient emissions were measured using fast response gas analyzers, with time response giving resolution at better than engine firing frequency.

The control of transient emissions from turbocharged diesel engines remains an important objective to manufacturers, since newly produced engines must meet the stringent criteria concerning exhaust emissions levels as dictated by the legislated Transient Cycles. In the present work, experimental tests are conducted on a medium-duty, turbocharged and after-cooled diesel engine in order to investigate the behavior and formation mechanism of nitric oxide (NO), smoke and combustion noise emissions under various transient operating schedules including acceleration, load change and starting. To this aim, a fully instrumented test bed was set up in order to record and research key engine and turbocharger variables during the transient events. The main parameters measured were nitric oxide concentration and smoke opacity (both using ultra-fast response analyzers) as well as combustion noise.

This paper describes the application of a non-dispersive infrared-based instrument designed to measure CO with a response time of 7ms. Spark ignition engine emission measurements recorded during the first 505 seconds of an FTP75 drive-cycle for a 4 cylinder engine are presented, including fast response hydrocarbon and NO measurements. An analysis of the engine-out (pre-catalyst) exhaust gas is provided. Data collected simultaneously with a standard emissions test stand and conventional dilution tunnel are compared to the high frequency measurements. Fast CO analysis provides new insight into cold-start fuelling calibration and cylinder-to-cylinder AFR variation. Under rich conditions, the strong dependence of CO production on the quantity of excess fuel allows a significantly faster estimate of engine stoichiometry than a UEGO sensor.

An on-board version of a fast response chemiluminsescence analyzer with a 3-millisecond response time enables the recording of high temporal resolution transient NOx emissions during cold start and pull-away, gear changes, speed bumps and other real world transient conditions. Tests were initially performed on a 1.6 litre turbo GDI vehicle before comparison with a diesel vehicle. The data has been correlated with on-board engine data available from the vehicle’s electronic control unit to study the underlying causes of these short-duration events. Exhaust gas was generally sampled from downstream of the after treatment system but before the silencer (muffler) to preserve all high frequency detail and to allow accurate integration of pollutant concentration and engine exhaust mass flow.

An accurate prediction of residual burned gas within the combustion chamber is important to quantify for development of modern engines, especially so for those with internally recycled burned gases and HCCI operations. A wall-guided GDI engine has been fitted with an in-cylinder sampling probe attached to a fast response NDIR analyser to measure in-situ the cycle-by-cycle trapped residual gas. The results have been compared with a model which predicts the trapped residual gas fraction based on heat release rate calculated from the cylinder pressure data and other factors. The inlet and exhaust valve timings were varied to produce a range of Residual Gas Fraction (RGF) conditions and the results were compared between the actual measured CO2 values and those predicted by the model, which shows that the RGF value derived from the exhaust gas temperature and pressure measurement at EVC is consistently overestimated by 5% over those based on the CO2 concentrations.

The gaseous and particulate emissions from a diesel passenger car have been studied during cold start and Diesel Particulate Filter (DPF) regeneration events occurring during the New European Drive Cycle (NEDC). During the initial phase of the cycle, Diesel Oxidation Catalyst (DOC) light-off was seen to be highly dynamic with catalyst efficiency changing dramatically with changes in catalyst temperature. Accumulation mode particulate emissions were sampled directly from the exhaust after the DPF. From cold start with a clean (regenerated) DPF, accumulation mode particle emissions were seen to be very much higher than those from a loaded DPF. This accumulation mode slip lasted only approximately 200 seconds. During regeneration of the DPF, the oxidation of trapped soot was associated with a large tailpipe emission of nucleation mode particles.

Cyclic combustion variability (CCV) is an undesirable characteristic of spark ignition (SI) engines, and originates from variations in gas motion and turbulence, as well as from differences in mixture composition and homogeneity in each cycle. In this work, the cycle to cycle variability on combustion and emissions is experimentally investigated on a high-speed, port fuel injected, spark ignition engine. Fast response analyzers were placed at the exhaust manifold, directly downstream of the exhaust valve of one cylinder, for the determination of the cycle-resolved carbon monoxide (CO) and nitric oxide (NO) emissions. A piezoelectric transducer, integrated in the spark-plug, was also used for cylinder pressure measurement. The impact of engine operating parameters, namely engine speed, load, equivalence ratio and ignition timing on combustion and emissions variability, was evaluated.

Ammonia (NH3) is a carbon-free fuel, which could partially or completely eliminate hydrocarbon (HC) fuel demand. Using ammonia directly as a fuel has some challenges due to its low burning speed and low flammability range, which generates unstable combustion inside the combustion chamber. This study investigated the effect of two different compression ratios (CRs) of 10.5 and 12.5 on the performance of ammonia combustion by using a conventional single spark-ignition (SI) approach. It was found that at a lower CR of 10.5, the combustion was unstable even at advanced spark timing (ST) due to poor combustion characteristics of ammonia. However, increasing the CR to 12.5 improved the engine performance significantly with lower cyclic variations. In addition, this research work also observed the effect of multiple spark ignition strategies on pure ammonia combustion and compared it with the conventional SI approach for the same operating conditions.

Ammonia as a fuel suffers from a high ignition energy requirement making it hard to ignite in stoichiometric mixtures, especially with normal spark plugs. On the other hand, pre-chambers are proven to provide high ignition energy by producing multiple ignition spots in the main chamber. A pre-chamber is usually categorized as “active” if it has a dedicated fueling system, and as “passive” if it depends solely on the air- fuel mixture being introduced from the main chamber and is therefore simpler than the active type. In this study, an SI light-duty engine was tested with a conventional spark plug with fuel mixtures of gasoline and gaseous ammonia (0%, 25%, 50%, 75%, 90%, and 100% NH3). The test was then repeated with a passive pre-chamber under the same operating conditions for comparison. Moreover, the engine exhaust was fitted with a fast response analyzer to measure NOX. The use of the conventional spark plug showed stable combustion throughout the fuel mixture sweep.