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Lean NOx traps were tested under various laboratory and engine dynamometer conditions to assess the effects of sulfur, temperature, and other exhaust gas parameters on their NOx efficiency and durability. Most recent vendor supplied NOx trap materials have shown significant temperature durability improvements, but sulfur tolerance has remained unchanged. Trap samples were subjected to sulfur poisoning and were desoxed at high temperatures and at various air to fuel ratios. It was found that a simple sulfate model of sulfur interaction with the NOx trapping specie is not sufficient to explain the sulfur interactions observed.

A proportional sampler for vehicle feedgas and tailpipe emissions has been developed that extracts a small, constant fraction of the total exhaust flow during rapid transient changes in engine speed. Heated sampling lines are used to extract samples either before or after the catalytic converter. Instantaneous exhaust mass flow is measured by subtracting the CVS dilution air volume from the total CVS volume. This parameter is used to maintain a constant dilution ratio and proportional sample. The exhaust sample is diluted with high-purity air or nitrogen and is delivered into Tedlar sample bags. These transient test cycle weighted feedgas samples can be collected for subsequent analysis of hydrocarbons and oxygenated hydrocarbon species. This “mini-diluter” offers significant advantages over the conventional CVS system. The concentration of the samples are higher than those collected from the current CVS system because the dilution ratio can be optimized depending on the fuel.