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A mobile laboratory was designed and built in Helsinki Polytechnic, in close co-operation with the University of Helsinki, to measure traffic pollutants with high temporal and spatial resolution under real world conditions. The laboratory provides measurements of gaseous pollutants and particle size number distributions as well as meteorological and geographical parameters. Two inlet systems are employed to enable the “chasing” of different type of vehicles. This paper introduces the construction and technical details of the mobile laboratory, and presents the results from “chasing” experiments performed in the Helsinki metropolitan area during a field campaign in June, 2003. New particle formation was found while driving in the exhaust plume of vehicles. Approximately 75% of the total particle number concentration was due to particles smaller than 50 nm in size.

Because of the great interest in biodiesel fuels around the world, the International Energy Agency's Committee on Advanced Motor Fuels sponsored this project to determine emissions and performance of a number of biodiesel fuels with a special emphasis on unregulated emissions. Oak Ridge National Laboratory (ORNL) and Technical Research Centre in Finland (VTT) carried out the project with complementary work plans. Several different engines were used between the two sites, and in some cases emissions control catalysts were used, both at ORNL and at VTT. ORNL concentrated on light and medium duty engines, while VTT emphasized a heavy-duty engine and also used a light duty car as a test bed. Common fuels between the two sites for these tests were rape methyl ester in 30% blend and neat, soy methyl ester in 30% blend and neat, used vegetable oil methyl ester (UVOME) in 30% blend, and the Swedish environmental class 1 reformulated diesel (RFD).

Electrical low pressure impactor ELPI was modified to measure particles below 30 nanometers in aerodynamic diameter. This was accomplished by adding a filter stage to collect and measure nanoparticles. The charging unit of the instrument was modified to increase the charging efficiency of the smallest, nanometer sized, particles. The modified charging unit was calibrated and the new construction of the ELPI was tested in laboratory and in vehicle dynamometer test cell. Measurements performed in the engine test cell showed that modifications improve the size range and measurement capability of the ELPI for engine emissions.

New method to define the particle effective density as a function of particle size has been applied to diesel vehicle exhaust particles. The results show that, the effective density of agglomerated diesel particles decreases as a function of particle size. The density of primary particles varies from 1.1 to 1.2 g/cm3. Also the effect of used dilution method and fuel type on particle density was studied. The dilution effect seems to have stronger effect on particle effective density and structure than the fuel type.

Exhaust emissions from cars using reformulated gasoline (RFG) that meets European 2005 regulations for gasoline quality were compared to the emissions from cars using gasoline that meets European 2000 regulations (EU2000). Methyl Tertiary Butyl Ether (MTBE) and Tertiary Amyl Methyl Ether (TAME) were used as oxygenates in the reformulated gasoline. The EU2000 gasoline contained no oxygen. Regulated, particulate and PAH exhaust emissions were measured at 22°C for 7 cars and at -7°C for 5 cars using the European MVEG cycle for year 2000 (ECE+EUDC). One of the cars was equipped with a lean burn engine, one with a direct injection engine and one was a carburetor equipped car without a catalytic converter. All other cars were equipped with multi point port fuel injection and a catalytic converter. Mutagenic activity of particulate mass was evaluated using the Ames test.

The Technical Research Centre of Finland has carried out tests evaluating the emission performance (regulated and unregulated) of alternative fuels for light-duty applications for the International Energy Agency (IEA). Several technologies were tested under varying environmental conditions using the same methodology. Altogether 14 light-duty vehicles on gasoline, diesel, alcohol and gaseous fuels were tested, and the number of test combinations (vehicles/fuels/temperatures) was 143. The differences between all fuel alternatives using three-way catalyst (TWC) technology (and also diesel) are rather limited. However, when temperature is lowered and also unregulated emissions are considered, the situation changes somewhat. The gaseous fuels come out as winners giving by far the lowest overall emissions.

The purpose of our study was to investigate the effects of TAME and heavier ethers on reformulated gasoline. The research work focused on the comparison of Californian Phase 2 gasoline (CARB), current Finnish reformulated gasoline containing MTBE (RFG1), or MTBE+TAME+heavier ethers (RFG2) with non-oxygenated Eurograde gasoline (EN228). Significant reductions in exhaust emissions were achieved with all reformulated fuels when compared to the Eurograde fuel. For instance, benzene emissions were reduced as much as 40 to 50 % for all cars at two temperatures and the emissions of total toxics were reduced by 14 to 45 % depending on vehicle type and temperature. The lowest 1,3-butadiene emissions were achieved with CARB gasoline. The amount of PAH compounds in the particulate matter from the non-catalyst vehicle was lower with the reformulated fuels than with the Eurograde fuel.

Unregulated emissions of reformulated diesel fuels (sulfur < 50 ppm, aromatics < 20 vol-%) were compared to the European EN590 specification fuel (sulfur < 500 ppm, aromatics < 35 vol-%) in three IDI passenger cars and one DI van using FTP and/or ECE/EUDC emission test procedures. The effect of reformulated diesel fuels on the mutagenicity of particulate soluble organic fraction (SOF) was studied. Fuel reformulation reduced particulate emissions in IDI cars. Reformulating fuel by decreasing heavier aromatics - without decreasing final boiling point - reduced particulate mutagenicity on emission basis. At low ambient temperature (-7°C) particulate PAH and mutagenic emissions increased compared to the standard ambient temperature (+22°C) with all fuels.

Emissions of heavy duty engines using hydrocarbon fuels and rape seed methyl ester (RME) were measured according to the ECE R49 test procedure. The effect of fuel density on engine power was taken into account in the ECE R49 tests. The two reformulated fuels tested had sulphur below 50 ppm, aromatics below 20 vol-%, cetane number over 49 and reduced triaromatic content. Particulates were measured in a AVL Mini Dilution Tunnel 474 and gaseous unregulated hydrocarbons by Siemens FTIR. Reformulation reduced NOx by 5 to 12 %, particulates by 10 to 25 % and Ames mutagenicity by 56 to 74 %. RME increased NOx by 4 to 9 %, reduced particulates by 0 to 33 % and the mutagenicity by 17 %. Cetane number was found to be not important in reducing emissions. Low fuel triaromatic and low particulate PAH content reduced the mutagenicity of particulates.

Cold operating environment has many kinds of negative effects on the use of automobiles. Low ambient temperature degrades start-up performance and increases fuel consumption. Hence, the amount of harmful exhaust emissions is also elevated. In particular, high concentrations of carbon monoxide (CO) and unburned hydrocarbons (HC) are present. The continuously widening implementation of US-type emission regulations around the world has brought emission control technology based on the use of three-way catalyst (TWC) even to the Nordic countries having cold climate. Cold-start increases emissions from conventional cars, and especially the performance of TWC type of emission reduction has been shown to be quite susceptible to low ambient temperature. Therefore, an increasing emphasis has been set to the testing of exhaust emissions also at sub-normal temperatures, i.e. below the range of +20 …+30°C widely designated by the legislative procedures.