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Absolute two-dimensional concentration distributions of nitric oxide have been measured in a fully transparent square piston engine with planar laser induced fluorescence. A calibration procedure was used to obtain absolute NO concentrations. The NO formation was studied in the propane/air fueled engine as a function of air/fuel ratio, crank angle and load. Simultaneous measurements of NO distributions by LIF and temperature fields via Rayleigh scattering allowed to study the correlation of NO formation and temperature. It was found that the measured NO was mainly formed via the Zeldovich mechanism.

2-dimensional time resolved (200 frames/s) flow field measurements have been made in a transparent SI square piston engine using a movie version of particle image velocimetry (PIV). To this end the beam of a copper vapor laser was formed into a light sheet and was double pulsed with a pulse separation of 50 μs at a repetition rate of 200 Hz. A rotating drum camera was used to record the Mie-scattered signals from seeding particles. The circumferential velocity of the drum of the camera causes an image shifting of the two exposures taken with a double pulse. By proper adaption of drum and engine speed, a series of up to 70 double pulsed images per individual engine cycle may be recorded on film. This film data may be evaluated uniquely with respect to both magnitude and direction of individual flow vectors in the flow field.

The fluorescence characteristics of different carbonyl compounds were investigated in a pressurized bomb using an excimer laser (308 nm) for excitation. The partial pressure of the carbonyl compounds and air was varied between 0 - saturation pressure and 0 - 5 bar, respectively. The fluorescence signal of different ketones increased almost linearly with vapour pressure. It was found to be almost independent of air pressure indicating only a weak quenching influence of oxygen. Ethylmethylketone (EMK) has a boiling temperature and vapour pressure similar to gasoline. Therefore, the applicability of EMK for measuring 2-D fuel distributions in a combustion chamber was tested in a transparent SI square piston engine. EMK was injected into the intake manifold by a conventional injector for studying the fuel/air mixing during the intake and compression stroke at 1.000 rpm. From the 2-D fluorescence signals 2-D air/fuel ratios were calculated using calibration data from bomb experiments.