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In this study, the particle emission characteristics of 10% alternative diesel fuel blends (Rapeseed Methyl Ester and Gas-to-Liquid) were investigated through the tests carried out on a light duty common-rail Euro 4 diesel engine. Under steady engine conditions, the study focused on particle number concentration and size distribution, to comply with the particle metrics of the European Emission Regulations (Regulation NO 715/2007, amended by 692/2008 and 595/2009). The non-volatile particle characteristics during the engine warming up were also investigated. They indicated that without any modification to the engine, adding selected alternative fuels, even at a low percentage, can result in a noticeable reduction of the total particle numbers; however, the number of nucleation mode particles can increase in certain cases.

The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.

In the present work, the partial oxidation of diesel (US07), rapeseed methyl ester (RME) and low temperature Fischer - Tropsch synthetic diesel (SD), almost 100% paraffinic, was investigated for the purpose of hydrogen and intermediate hydrocarbon species production over a prototype reforming catalyst, for the potential use in hydrocarbon selective catalytic reduction (HC-SCR) of nitrogen oxide (NOx) emissions from diesel engines. The presence of small amounts of hydrogen can substantially improve the effectiveness of hydrocarbons in the selective reduction of NOx over lean NOx catalysts, particularly at low temperatures (150-350°C). In this study, the partial oxidation reactor was operating at the same input power (kW), based on the calorific values of the fed fuel. Hydrogen production was as high as 19%, from the partial oxidation of SD fuel, and dropped to 17% and 14% for RME and US07 diesel, respectively.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

It is known that the levels of hydrocarbon (HC) emissions from Homogeneous Charge Compression Ignition (HCCI) engines are relatively higher than that of Spark-Ignition (SI) engines because of the lower combustion temperature. In order to improve understanding of the mechanisms and products of HCCI combustion in comparison with SI combustion, a quantitative analysis of individual hydrocarbons in the C1 - C6 range emitted in the exhaust gases of gasoline direct injection V6 engine operating in SI and HCCI modes with cam profile switching has been carried out using gas chromatography - mass spectrometry (GCMS) apparatus attached on-line to engine exhaust. In this study, with a GC run time of 20 minutes all aliphatic and olefinic hydrocarbon species in the range C1 to C6 are resolved.

Increasing biodiesel content in mineral diesel is being promoted considerably for road transportation in Europe. With positive benefits in terms of net CO2 emissions, biofuels with compatible properties to those of conventional diesel are increasingly being used in combustion engines. In comparison to standard diesel fuel, the near zero sulphur content and low levels of aromatic compounds in biodiesel fuel can have a profound effect not only on combustion characteristics but on engine-out emissions as well. This paper presents analysis of particulate matter (PM) emissions from a turbo-charged, common rail direct injection (DI) V6 Jaguar engine operating with an RME (rapeseed methyl ester) biodiesel blended with ultra low sulphur diesel (ULSD) fuel (B30 - 30% of RME by volume). Three different engine load and speed conditions were selected for the test and no modifications were made to the engine hardware or engine management system (EMS) calibration.

Producing on-board the hydrogen that is to be used as supplementary fuel by exhaust gas reforming of gasoline shows encouraging results. Extensive research has been done at the University of Birmingham towards on board generation of hydrogen-rich gaseous fuel. Exhaust gas reforming which utilizes water vapor and enthalpy from the hot engine exhaust gas was applied using a compact system of a fuel reformer reactor integrated with the three way catalytic converter (TWC). Such system can be fitted in the limited space close to the engine. The device has been designed and built in concentric shape with the catalytic converter as a core and the reformer in an annular shape outside, to best utilize the waste heat from the catalytic converter. It requires very little extra space beyond the baseline catalytic converter.

Previous work of the authors' group has shown that biodiesel fuels as a replacement for conventional diesel fuel in engine combustion can reduce PM level dramatically while lowering some other regulated emissions as well. It has shown that these fuels have the potential to increase the overall engine performance due to their lower sulphur and/or aromatics content compared with standard diesel fuels. This paper presents a study on a single cylinder naturally aspirated direct injection (DI) diesel engine, equipped with a pump-line-nozzle injection system, operating with varied biodiesel fuel blends (0%, 25%, and 50% of RME by volume) with ultra low sulphur diesel fuel (ULSD). The detailed analysis of the measurement data shows that the ignition delay and exhaust emissions are affected by the proportion of biodiesel due to the effect of different physical and chemical properties of the two fuels.

With the high auto ignition temperature of natural gas, various approaches such as high compression ratios and/or intake charge heating are required for auto ignition. Another approach utilizes the trapping of internal residual gas (as used before in gasoline controlled auto ignition engines), to lower the thermal requirements for the auto ignition process in natural gas. In the present work, the achievable engine load range is controlled by the degree of internal trapping of exhaust gas supplemented by intake charge heating. Special valve strategies were used to control the internal retention of exhaust gas. Significant differences in the degree of valve overlap were necessary when compared to gasoline operation at the same speeds and loads, resulting in lower amounts of residual gas observed. The dilution effect of residual gas trapping is hence reduced, resulting in higher NOx emissions for the stoichiometric air/fuel ratio operation as compared to gasoline.

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.