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This is a follow-up report about the development of a cost-effective Palladium (Pd) zeolite-based (HC/NOx trap type) cold-start catalyst (CSC) [1] to meet the future more stringent Chinese vehicle tailpipe emission standard. The impacts of Pd /stabilizer combination within zeolite for the HC/NOx trapping efficiency, the high temperature aging and the durability of the CSCs will be demonstrated by the laboratory results within this paper. The feasibility of a Cu zeolite, a popular non-precious metal ion- zeolite CSC for vehicle applications with respect to cost saving options will be demonstrated. A more complete picture of the effects of PGM/stabilizer within the zeolite to the functions of a CSC will also be summarized in this paper. All results indicate clearly that without the PGM/stabilizer within the zeolite, it would be difficult for the zeolite-based HC/NOx trap type CSC catalyst to be practically used for a vehicle application.

In order to get a better understanding of the mechanical behavior of lithium-ion battery cells, especially for the mechanical anisotropy and dynamic effect, a series of tests for quasi-static indentation and dynamic impact tests has been designed. In the study, mechanical indentation tests with different indentation heads, different loading directions and different impact speeds were performed on a type of large format prismatic lithium-ion battery cells and jellyrolls of them. To mitigate thermal runaway, only fully-discharged cells and jellyrolls were used. The force-displacement response and open circuit voltage (OCV) were recorded and compared. It shows that jellyroll and battery cell have apparent mechanical anisotropy and strain-rate effect. The stiffness of jellyroll and cell in out-of-plane direction is much larger than that in two in-plane directions.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III/Tier III Emissions Standards for Light Duty Diesel (LDD) passenger vehicles. As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, durability and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR). The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) provided as Diesel Exhaust Fluid (DEF), which is an aqueous urea solution 32.5% concentration in weight with water (CO(NH2)2 + H2O), optimum operating temperatures, and optimum nitrogen dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is most influenced by Precious Group Metals (PGM) containing catalysts upstream of the SCR catalyst.

Investigations of on-road emissions performance of vehicles have been made using various methods and instrumentation, some of which are very complex and costly. For the particular case of NOx emissions on Diesel road vehicles equipped with SCR catalysts (Selective Catalytic Reduction), many of these vehicles are equipped with NOx sensor(s) for the purpose of OBD (On-Board Diagnostics), and the ECU (Engine Control Unit) makes this data available via the diagnostic connector under the SAEJ1979 protocol for light duty vehicles. Data for mass air flow and fuel flow are also available per J1979, so the ongoing NOx mass flow can be estimated when the NOx sensors are active with no additional instrumentation. Heavy duty pickup trucks with SCR systems from 3 major US manufacturers, each certified to the optional chassis certification of 0.2 g/mi NOx on the FTP75, were obtained to be evaluated for SCR system behavior under normal driving conditions.

The introduction of stringent EPA 2015 regulations for locomotive / marine engines and IMO 2016 Tier III marine engines initiates the need to develop large diesel engine aftertreatment systems to drastically reduce emissions such as SOx, PM, NOx, unburned HC and CO. In essence, the aftertreatment systems must satisfy a comprehensive set of performance criteria with respect to back pressure, emission reduction efficiency, mixing, urea deposits, packaging, durability, cost and others. For on-road and off-road vehicles, urea-based SCR has been the mainstream technology to reduce NOx emissions. For category II marine engines with single cylinder displacement volumes between 7 liters and 30 liters, IMO III (Tier IV) emission regulations dictate approximately 80% reduction of NOx emissions vs. Tier II emission regulations [1]. Urea / ammonia SCR is being considered as an enabling technology to achieve IMO III regulations without significant impacts on engine performance and fuel economy.

An optimal idle speed control (ISC) system for an automotive engine is introduced in this paper. The system is based on a non-linear model including time delay. This model is linearized at the nominal operating point. The effect of the time delay on control is compensated by prediction. This methodology is applied to a Chrysler 2.0 liter 4-cylinder SOHC (Single Overhead Cam) engine. All of the unknown parameters of the model are identified by using the normal operating data from the test engine. Based on these identified parameters, an optimal controller was designed and implemented using a rapid prototyping system. Numerous experiments of the optimal controller were carried out at the Chrysler Technology Center in Auburn Hills, Michigan. The performance was compared to that of the existing controller. The results showed that the optimal controller has the capability to effectively control the engine idle speed under a variety of accessory loads and disturbances.