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Technical Paper

Thermodynamic Analysis of Fuel Processing

1999-03-01
1999-01-0538
Thermodynamic analysis of equilibrium products and heat requirements is conducted for C8H18 (octane), CH4O (methanol), C2H6O (ethanol) and C3H8 (propane) at specified temperature and pressure. The equilibrium calculation utilizes the NASA equilibrium code by Gordon and MacBride. The temperature range is from 600 to 1700 K, and the pressure is set at 1 bar. The equilibrium calculation shows that the adiabatic temperatures are generally below 1300 K, except for C2H6O and C3H8 at their respective partial oxidation conditions considered in this paper. Calculation also shows that the presence of H2O in the reactant mixture yields high conversion of H2 at temperature above 1200 K, and above which the H2 mole fraction is relatively independent of the mixture temperature. Negligible C(graphite) is predicted for conditions with temperature above 1200 K.
Technical Paper

Modeling and Optimization of a PEMFC Catalyst Layer

1999-03-01
1999-01-0539
Two mathematical models for the catalyst layer of a PEMFC, i.e. the macro-homogenous model and the agglomerate model are evaluated in this paper. The characteristics of both models and the application of both models to optimal design of catalyst layer are discussed. The one-dimensional governing equations of both models are solved analytically or numerically using the finite difference method. A simplified, analytic solution of the macro-homogenous model under ideal conditions is derived. Parametric study and sensitivity analyses are performed for the agglomerate model to identify the parameters that have significant influences on the performance of a PEMFC. Several parameters including the electrolyte thickness, porosity, oxygen permeability, and layer thickness are found to affect the limiting current significantly. A solid model is developed to visualize the structure of a catalyst layer. This solid model is used to estimate effective transport properties.
Technical Paper

A Study of Aspiration Effects in Reduced-Scale Model Airbag Modules

1998-09-29
982324
One-sixth scale model airbag modules have been used to investigate flow aspiration effects in passenger-side airbag modules. A similarity analysis between flows in the model and the prototype unit assures reasonable approximation of the actual flows. In the controlled flow environment of the model, flow visualization suggests that the underexpanded jet structure follows the universal relationship based on experimental data and shows that aspiration occurs through the aspiration holes. Detailed velocity measurements provide the ratio of the mass added to the discharged gas for a single firing. The same approaches can be applied in the design of full-scale airbag systems.
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