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Technical Paper

Effect of Gasoline Components on Exhaust Hydrocarbon Components

1993-10-01
932670
Vehicle emissions tests were conducted using a 1992 model year Toyota Camry for California under the 1975 Federal Test Procedure. Nine fuels of different composition were prepared. Effects of gasoline composition and sulfur content on tailpipe and engine-out emissions were investigated. Exhaust mass emission test results indicated that gasoline distillation properties and sulfur content have large effect on non-methane organic gas emissions. Furthermore, fuel, engine-out, and tailpipe hydrocarbons were speciated and the relationship between fuel and exhaust specific ozone reactivity analyzed. From these studies, it is concluded that aromatics are the largest contributor to the specific ozone reactivity of exhaust emissions and these aromatics, in emissions, are mainly unburned and partly oxidized aromatics from the fuel. Fuel MTBE correlates with exhaust olefins and oxygenates.
Technical Paper

Effects of California Phase 2 Reformulated Gasoline Specifications on Exhaust Emission Reduction

1992-10-01
922179
In response to various reformulated gasoline regulations, several studies have been conducted to evaluate the relationship between fuel properties and vehicle exhaust emissions. These studies, however, have focused on the fuel effect and have not examined the most promising advanced technology emission control systems on low emission vehicles. Toyota's reformulated gasoline research first set out to study the effect fuel compositions has on 2 different emission control systems. On both systems, non-methane hydrocarbon (NMHC) emissions were significantly affected by the 50% and 90% distillation temperature (T50 and T90). A correlation was also found exhaust olefine content and the amount of MTBE contained in the fuel. Research was also conducted on the specific ozone reactivity (SOR) of exhaust hydrocarbons. Various fuels with similar specifications but blended from different feedstocks were evaluated.
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