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For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

Catalytic performance can be improved by reducing heat capacity and increasing geometric surface area (GSA). The effects of the catalyst layout and the substrate cell structure were investigated on the catalytic performance. The catalyst layout covers an under-floor catalyst only, a close-coupled catalyst with an under-floor catalyst and a close-coupled catalyst only, and a dual-bed close-coupled catalyst only. The substrate cell structure covers from conventional 6 mil/ 400 cpsi substrate to the ultra thin-wall and high cell-density substrate of 2 mil/ 900 cpsi. Significant reduction of emissions can be achieved by moving the catalyst location upstream of the exhaust gas and combined with using the ultra thin-wall and high cell-density substrates. Furthermore, dual-bed design demonstrated further improvement of catalytic performance at close-coupled location.

Catalytic performance can be improved by increasing geometric surface area (GSA) and reducing bulk density (BD), namely heat capacity, using high cell-density / thinwall advanced ceramic substrates. The advanced substrates, such as 3 mil/600 cpsi and 2 mil/900 cpsi have improved the catalytic performance over the conventional substrates, and are expected to help in complying with future emission regulations, as well as catalyst downsizing. This paper describes the effects of GSA and BD using Pd-based catalysts. The reduction of hydrocarbons emissions was demonstrated significantly at close-coupled location, and dual bed design was proven effective. The effectiveness at under-floor location was not as significant as the close-coupled location.

This paper proposes a high temperature manifold converter with a thin wall ceramic substrate, such as; 4mil/400cpsi and 4mil/600cpsi. Double-wall cone insulation design was proposed for close-coupled converters to protect the conventional intumescent mat from high temperature. However, the double wall cone insulation is not applicable when the converter is directly mounted to the exhaust manifold without an inlet cone. The prototype manifold converter was tested under hot vibration test with a non-intumescent ceramic fiber mat and retainer rings as a supplemental support. The converter demonstrated durability for 10 hours under 80G acceleration and 100 hours under 60G acceleration with 1,050 °C catalyst bed temperature. The skin temperature of the heat shield was kept below 400 °C.

The first two of a series of traps retrofitted on a pilot fleet of 110 buses of the Athens Bus Corporation were removed for examination after 100,000 km of revenue service. These buses were gradually equipped with the ELBO Trap Oxidiser since the beginning of 1989 and are constantly operated on Cerium based fuel additive. The physical properties and the chemical composition of filters and ash residues were analysed by the filter manufacturers and the fuel additive producer. The results have shown that after two years of operation the filter material remained intact and the ash deposits (consisting mainly of CeO2) exhibit a limited interaction with the cordierite. More than 94% of these deposits are filtered by the monoliths and could be removed to a large extent with the application of conventional methods.