Technical Paper
Low Emission Three-way Catalyst and OSC Material Development for OBD Diagnostics
1999-10-25
1999-01-3625
The development of efficient, durable three-way catalysts with OBD facilities needs cooperation between different areas related to engine, control and catalyst technologies. High-loading Pd and Pd-Rh precatalysts with λ sensors upstream and downstream were evaluated in FTP cycle to find out the appropriate driving conditions for OBD-II. Diagnostic values were calculated by the damping of λ responses caused by the aged precatalyst. The ratio of oxygen storage capacity (OSC) and precious metals were studied to improve the correlation between calculated diagnostic values and the catalyst efficiency. In fact, the correlation from diagnostic values was better to NOx than to THC efficiency by bag 1 and 2 emissions in FTP 75. The amplitude method with two λ sensors over warm converters is commonly used for OBD but hydrocarbon emissions are mainly formed during cold-start periods. Therefore the OBD calibration and catalyst optimal compositions have conflicting demands.
