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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

Computer controls are increasingly being employed in systems ranging from simple to very complex. A new trend is to extend these computer systems to include monitoring schemes to detect malfunctions. An example is provided by new automobiles sold in the US, Canada, and Europe. By law they must include “on-board diagnostics” designed to detect certain malfunctions in the powertrain system that may cause excessive emissions. The present article outlines some of the fundamental concepts of system's monitoring and general principles for the design of such monitors.