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This paper presents the results of emission tests of a flexible fuel vehicle (FFV) powered by an SI engine, fueled by M85, and supplied with oxygen-enriched intake air containing nominal 21%, 23%, and 25% oxygen (by volume). Emission data were collected by following the standard federal test procedure (FTP) and U.S. Environmental Protection Agency's (EPA's) “off-cycle” test EPA-REP05. Engine-out total hydrocarbons (THCs) and unburned methanol were considerably reduced in the entire FTP cycle when the oxygen content of the intake air was either 23% or 25%. However, CO emissions did not vary appreciably, and NOx emissions were higher. Formaldehyde emissions were reduced by about 53% in bag 1, 84% in bag 2, and 59% in bag 3 of the FTP cycle when 25% oxygen-enriched intake air was used.

Oxygen-enriched combustion is a proven, seriously considered technique to reduce exhaust hydrocarbons (HC) and carbon monoxide (CO) emissions from automotive gasoline engines. This paper presents the cold-phase emissions reduction results of using oxygen-enriched intake air containing about 23% and 25% oxygen (by volume) in a vehicle powered by a spark-ignition (SI) engine. Both engine-out and converter-out emissions data were collected by following the standard federal test procedure (FTP). Converter-out emissions data were also obtained employing the U.S. Environmental Protection Agency's (EPA's) “Off-Cycle” test. Test results indicate that the engine-out CO emissions during the cold phase (bag 1) were reduced by about 46 and 50%, and HC by about 33 and 43%, using nominal 23 and 25% oxygen enriched air compared to ambient air (21% oxygen by volume), respectively. However, the corresponding oxides of nitrogen (NOx) emissions were increased by about 56 and 79%, respectively.

An analytical program has been developed to identify approximately 225 compounds that may exist in automotive gasoline engine exhaust and evaporative emissions. This method combines five separate gas chromatographic analyses and a high performance liquid chromatographic analysis. It provides for independent determinations of benzene, toluene, ethers, and alcohols to minimize interferences during the capillary separations. Also provided is the determination of 2,2,3-trimethylpentane using the toluene analysis, instead of providing only a combined value for these coeluting compounds. The data from these several separate analyses are combined to provide a final speciation report giving mg/mile values for each compound or compound group. This type of data is used to study the effects of gasoline compositional changes on emissions and on ozone formation, especially when combined with the speciated analysis of the gasoline.