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Zinc dialkylphosphate (ZP), a sulfur free analogue of Zinc dialkyldithiophosphate (ZDTP) has been synthesized and tested for engine oil application. The sulfur free engine oil based on ZP showed excellent TBN retention and engine cleanliness in several engine tests which were operated at low and high temperatures. A prototype low phosphorus (0.05%) and low sulfated ash (0.5%) engine oil exhibited even better longer drain performance than a fully synthetic engine oil containing 0.1% P and 1.1% sulfated ash. Thus, zinc dialkylphosphate can be a promising candidate as a ZDTP substitute for future catalyst system compatible engine oil.

A high viscosity index (HVI) petroleum base stock (VI=125), which is produced by a severe hydrocracking process, has been used in formulating an advanced SAE 5W-30 oil meeting API SG, EC-II and current ILSAC performance requirements in order to demonstrate potential fuel economy benefits of this oil. The oil was formulated by blending the HVI base stock with a small amount of a solvent-refined base stock to obtain an “optimal aromaticity”, a dispersant VI improver, an optimized combination of detergent and inhibitor, and a conventional ashless friction modifier. The fuel economy performance of this oil has been compared to that of a similarly formulated solvent-refined SAE 5W-30 oil using the Sequence VI test, a motored engine friction test, a new fired/motored friction test, and the EPA road simulator fuel economy test. The SAE 5W-30 HVI oil exhibited an improved fuel economy performance in the above tests, despite of higher HTHS viscosity of the HVI oil.