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Sulfur containing species as well as other polar molecules provide lubricity and thermal stability to diesel fuels. During the refining process to produce low and ultra-low sulfur diesel fuels, these components are removed. As a result, fuel additives such as lubricity agents and antioxidant may be added to protect fuel stability and prevent fuel pump wear. Some lubricity additives, such as dimer acids, resulted in fuel filter plugging. The plugging mechanism was related to the capability of aliphatic acids to form agglomeration by interactions with the overbased detergents, delivered into the fuel as oil contaminants. Other sources of acids, derived from thermal degradation, can lead to the same problem. In this study, individual lubricant additives were mixed in the fuel to form single- and dual-component systems. Levels of compatibility and amounts of interaction products were evaluated for individual solutions.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

Heavy Duty diesel engines typically use roller followers in contact with the cam to reduce friction and accommodate high Hertzian stresses. When the rolling contact slips into sliding, cam galling can occur that may lead to major cam failures. Oil traction has been identified as a possible source to cause slipping. In this study, oil traction was first measured in a Mini Traction Machine (MTM). The results were then validated by a series of engine tests to show that the measured oil traction correlated with the occurrence of cam galling. Finally, the MTM was used to evaluate various engine oil formulations. It is concluded that some advanced base oils, if not properly compensated by the additive package, exhibit dangerously low oil traction. Oil traction needs to be part of the oil formulation considerations.

The study described in this paper covers the development of the Sequence IVB low-temperature valvetrain wear test as a replacement test platform for the existing ASTM D6891 Sequence IVA for the new engine oil category, ILSAC GF-6. The Sequence IVB Test uses a Toyota engine with dual overhead camshafts, direct-acting mechanical lifter valvetrain system. The original intent for the new test was to be a direct replacement for the Sequence IVA. Due to inherent differences in valvetrain system design between the Sequence IVA and IVB engines, it was necessary to alter existing test conditions to ensure adequate wear was produced on the valvetrain components to allow discrimination among the different lubricant formulations. A variety of test conditions and wear parameters were evaluated in the test development. Radioactive tracer technique (RATT) was used to determine the wear response of the test platform to various test conditions.

Corrosive wear of non-ferrous engine components by lubricants is a concern of all major heavy duty diesel engine manufacturers since warranty on key engine components has been extended to 500,000 miles. Several commercial lubricants have been linked to premature cam and rod bearing failures induced by corrosion in certain fleets. Although the overall failure rate is low, specific fleets have experienced significantly higher failure rates due to the lubricants used. These failures usually occur at high mileages but less than 500,000 miles. This kind of slow corrosion easily escapes detection of engine tests contained in current oil specifications, and it represents a serious issue in long term warranty cost to diesel engine manufacturers. A comprehensive fleet database has been established to identify the most corrosive lubricants. These lubricants have served as reference oils to develop a corrosion bench test.

The lubricity of low sulfur diesel fuel was evaluated using a Scuffing BOCLE device. Physical and chemical properties of diesel fuels were then used to correlate with fuel lubricity. It is concluded that lubricity is primarily determined by viscosity and di-aromatic content. A lubricity predictor (Lp) using a linear combination of the two parameters is proposed to predict fuel lubricity. These two parameters are interchangeable within normal ranges of viscosity and di-aromatic content of No.1 and No.2 diesel fuels. Fuel lubricity has been interpreted to be the result of hydrodynamic lubrication, which is largely a function of viscosity, and boundary lubrication, which is contributed to by the di-aromatic content.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

With the impending development of GF-6, the newest generation of engine oil, a new standardized oil oxidation and piston deposit test was developed using Chrysler 3.6 L Pentastar engine. The performance requirements and approval for passenger car light duty gasoline engine oil categories are set by the International Lubricants Standardization and Approval committee (ILSAC) and the American Petroleum Institute (API) using standardized testing protocols developed under the guidance of ASTM, the American Society for Testing and Materials. This paper describes the development of a new ASTM Chrysler oxidation and deposit test that will be used to evaluate lubricants performance for oil thickening and viscosity increase, and piston deposits.