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A thorough understanding of vehicle exhaust aftertreatment system performance requires time-resolved emissions measurements that accurately follow driving transients, and that are correctly time-aligned with exhaust temperature and flow measurements. The transient response of conventional gas analyzers is characterized by both a time delay and an attenuation of high-frequency signal components. The distortion that this imposes on transient emissions measurements causes significant errors in instantaneous calculations of aftertreatment system efficiency, and thus in modal mass analysis. This creates difficulties in mathematical modeling of emissions system performance and in optimization of powertrain control strategies, leading to suboptimal aftertreatment system designs. A mathematical method is presented which improves the response time of emissions measurements. This begins with development of a model of gas transport and mixing within the sampling and measurement system.

A hydrocarbon trapping system for cold start emissions was constructed and tested using two types of carbonaceous adsorbents provided by Corning, Inc. One was made by combining activated carbon with an organic binder and extruding it into a honeycomb, and the other by depositing a carbon coating on a ceramic monolith. The tests were carried out on an engine in a dynamometer laboratory to characterize the performance of the carbon elements under transient cold start conditions. Performance was evaluated by continuously measuring exhaust gas hydrocarbon concentrations upstream and downstream of the trap, using conventional emissions consoles. Samples were also collected for off-line analysis of individual hydrocarbon species using gas chromatography to examine differences in adsorption of individual species. The speciated hydrocarbon data were used to distinguish between the mass trapping efficiency and a reactivity-based trapping efficiency of the adsorbant traps.