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We developed new single coated Pd/Rh three-way catalysts (TWC). Several Pd/Rh single layered catalysts were prepared by changing the precious metal (PM) fixation method and adding new base metal oxides (BMO). These samples were compared with double-coated catalyst by using model gas activity test, BET test, XRD test and vehicle emission test. It is found that the performance of the single coated catalyst is as good as that of commercialized double-coated catalyst. The oxygen storage capacity of the single coated catalyst is better than that of double-coated catalyst. Moreover, manufacturing the single coated catalyst enables us to eliminate the unnecessary coating process which is essential to the conventional one. Our test results demonstrate that the developed catalyst has sufficient activity and durability of OSC to meet emission and OBD-II regulations.

It is well known that the EHC (Electrically Heated Catalyst) is very effective for the reduction of cold-start hydrocarbon emissions. To optimize EHC applications for LEVI (Low Emission Vehicle) and ULEV (Ultra Low Emission Vehicle) standards, the effect of heating and secondary air injection on the emission purification efficiency in FTP (Federal Test Procedure) were evaluated with three different EHC system configurations. The exhaust manifold location EHC system in which the EHC with a light-off catalyst is installed near the exhaust manifold, yields 0.038g/mile of THC (Total Hydrocarbon emissions) when the test was performed according to the FFP with an engine-aged condition equivalent to 50,000miles. Therefore, the ULEV standards could be achieved through the system. A new battery system for the EHC and a single battery system for vehicle application were evaluated. Evaluation of the Ni-MH battery for EHC system is included.