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Technical Paper

Fluorocarbon and PTFE Thermodegradation and Contamination Modeling in a Space Habitat

1993-07-01
932146
The products of thermodegradation of fluorocarbon polymers (found in electrical insulation) will be toxic to space habitat crews, and the monitoring and detection of such contaminants are important to space environmental health. Experiments are therefore being performed on the thermodegradation of a liquid perfluoroalkane mixture (consisting of perfluorohexanes, C6F14, and −5% perfluoropentane, C5F12), similar in structure to polytetrafluoroethylene (PTFE - Teflon), in atmospheres of varying oxygen concentration. PTFE is a common material used on space vehicles for insulation of wires. When PTFE is thermally degraded, such as from the overheating of a wire and subsequent smoldering of the insulation, it may produce toxic compounds ranging from carbonyl fluoride and hydrogen fluoride through perfluorinated aromatic compounds to ultrafine particles.
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