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There are distinct operational mixture limits beyond which satisfactory spark ignition engine performance can not be maintained. The values of these limit mixtures which depend on the mode of their determination, are affected by numerous operational and design factors that include the type of engine and fuel used. Simple approximate methods are presented for predicting these limits. Good agreement is shown to exist between the calculated and the corresponding experimental values over a range of operating conditions while operating on the gaseous fuels: methane, propane and hydrogen. The experimentally observed operational limits deviate very substantially from the corresponding accepted flammability limit values for quiescent conditions evaluated at the average temperature and pressure prevailing at the instant of the spark passage.

The presence of carbon dioxide with methane is often encountered to varying proportions in numerous natural, industrial and bio-gases. The paper discusses how such a presence modifies significantly the thermodynamic, kinetic and combustion characteristics of methane in air. Experimental results are presented showing how the performance of engines, both of the spark ignition and compression ignition dual fuel types is adversely affected by the increasing presence of carbon dioxide with the methane. The bases for these trends are discussed and some guidelines towards alleviating the adverse effects of the presence of carbon dioxide in such fuel mixtures are made.

The observed lean and rich operational limits in a spark ignition engine of the variable compression ratio type fuelled with either methane or propane are shown to be amenable to correlation in terms of a calculated mean mixture temperature at the time of passing the spark. Moreover, using a detailed chemical kinetics model for the oxidation of lean methane-air mixtures in a compression ignition engine, the autoignition of methane-air mixtures is examined. It is shown that these autoignition limits are also influenced by the mean charge temperature and the kinetic and thermal sensitizing of the charge through mixing with residual gases.

There are numerous situations in a wide range of engineering applications involving combustion devices where the combustion of a fuel jet takes place in flowing streams containing varying proportions of a fuel homogeneously premixed with the surrounding air. Such applications can be found, for example, in dual fuel engines and in some gas turbine combustors. The paper describes some of the findings of an experimental investigation, supported by some analytical modeling, of the combustion of a circular gaseous fuel jet within lean homogeneous mixtures of various gaseous fuels and air. The nature of the combustion process of the pilot fuel jet, flame spread characteristics and limits within the surrounding moving atmosphere were considered in terms of the fuels used for the jet and the surrounding atmosphere and in terms of the jet discharge and surrounding stream flow characteristics.

The paper reviews the combustion characteristics of the two fuels and sets out to consider their respective performance in both spark ignition and compression ignition engines. Results of comparative tests involving spark ignition engines over a wide range of operating conditions are presented and discussed. Some of the performance characteristics considered are those relating to power output, efficiency, tendency to knock, cyclic variations, optimum spark requirements and exhaust emissions. Similarly, some of the performance characteristics in compression ignition engines considered include power output, efficiency, tendency towards knock and autoignition, exhaust emissions and low operational temperature problems. Finally, the relative operational safety aspects of the two fuels are evaluated. It is then suggested that in this regard, methane has some excellent physical, chemical and combustion characteristics that makes it a particularly safe fuel.