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The measurement protocol of solid particle number with the lower detection limit (D50) at 10 nm (SPN10) is planned to be implemented in European emission regulations by means of laboratory-grade measurement systems. Furthermore, SPN10 measurement as the real driving emissions (RDE) regulations is under development by defining appropriate technical specifications for the portable emissions measurement system (PEMS). It is under discussion to implement SPN10 limits as one of additional pollutants to the new European emissions regulations, so-called “Euro 7”. As the Consortium for ultra LOw Vehicle Emissions (CLOVE) has proposed, RDE testing by means of PEMS will be the primary means of emissions determination for certification purposes. Measurement equivalency between laboratory-grade emissions measurement systems and PEMS is still important due to the necessity of validation in laboratories before on-road testing by comparing determined emissions by both.

The Particle Measurement Programme (PMP) established under the United Nations Economic Commission for Europe has developed the solid particle number (PN) measurement methodology, which has relatively higher sensitivity than the particulate matter measurement protocol. The first PN emission regulation was introduced in 2011. The stationary PN measurement system (PMP system) has been applied in the chassis and the engine test cells. In recent years, real driving emissions (RDE) measurement is attracting attention. Portable emissions measurement systems for PN measurement (PN-PEMS) which can be installed on vehicles during RDE testing are available now. The European RDE regulation requires validation of PN-PEMS by comparing emission measurement results with a stationary PMP system on a chassis dynamometer prior to the on-road emissions testing. Measurement differences between the PN-PEMS and the PMP system has to be within the tolerance defined by the regulation.

Recently, it was reported that the atmospheric pollution levels of nitrogen dioxide (NO2) and particulate matter (PM) are not decreasing despite the introduction of stricter vehicle emission regulations. The difference between conditions of the test cycles defined by the vehicle emission regulations and the real driving can contribute to the differences between expected and actual pollution levels. This has led to the introduction of in-use vehicle emission monitoring and regulations by means of a portable emission measurement system (PEMS). An optimized on-board PM analyzer was developed in this study. The on-board PM analyzer is a combination of a partial flow dilution system (PFDS) particulate sampler and a diffusion charger sensor (DCS) for real-time PM signals. The measuring technology and basic performance of the analyzer will be explained. Acceleration of the vehicle can cause uncertainty of flow measurement in the PM sampler.

Portable emission measurement systems (PEMS) for particle number (PN) counting are under development in Europe, along with the vehicle testing protocol. A PN PEMS was developed by using a non-heated exhaust diluter, and applying a diffusion charger sensor (DCS) as the PN detector which is fitted with diffusion screens in order to selectively remove all particles, including volatiles, below 30 nm. Detection efficiencies of the DCS could be successfully adjusted by the number of diffusion screens installed before it. Equivalent results of the PN PEMS to a conventional system were observed by vehicle tests. However, variations were observed under specific vehicle operating conditions. Also, as part of the same program, a commercially available hand-held condensation particle counter (CPC) was compared with the standard CPC by vehicle tests as one of candidates to PEMS. Differences in PN concentrations were observed depending on the engine conditions

The subject of engine emissions is expected to be at the forefront of environmental regulations and consumers’ concerns for years to come. As technology develops to comply with new and different requirements in various regions of the world, understanding the fundamental principles of how engine emissions occur, and how they can be properly measured, is vitally important. Engine Emissions Measurement Handbook, developed and co-authored by HORIBA Automotive Test Systems team addresses the main aspects of this subject. Written with the technical user in mind, this title is a must-have for those involved in engine development and testing, and environmental researchers focusing on better ways to minimize emissions pollution.

Fuel efficiency is one of the most important parameters in advanced vehicles. Therefore, the measurement of fuel consumption in-situ and in real-time is obviously demanded in development and evaluation processes of new engines and vehicles. This paper describes a new concept for measuring fuel consumption in real-time, which utilizing raw exhaust gas flow rate and exhaust air-to-fuel ratio (AFR). The AFR is defined as the mass ratio of air and fuel supplied to the engine, and the mass flow rate of exhaust gas can be regarded as the summation of the mass flow rate of air and fuel. This means the fuel consumption can be calculated from exhaust flow rate and AFR. To realize in-situ, real-time measurement, we used an ultrasonic exhaust flow meter which can measure a wide flow range accurately with no pressure loss, and a fast response zirconia sensor which can be installed onto the exhaust pipe directly without any sampling system.

Conventional constant volume sampling (CVS) is well known as a precision emissions measurement method, even though the concentrations of THC, NOX, CO and CH₄ emitted from vehicles are getting lower by improvement of emissions control devices. Recently, fuel economy requirements have increased in many regions. Hybrid electric vehicle (HEV), or plug-in hybrid electric vehicle (PHEV), is one of the solutions for fuel economy improvement. HEVs and PHEVs have an all-electric range in which the internal combustion engines (ICEs) are completely shut down. This operation results in a high dilution factor (DF) and low concentrations of gaseous components, including CO₂, in the CVS system. Such dilution conditions directly cause an increase of numerical error for DF and an analysis error for gaseous components. Furthermore, a small amount of air flow across exhaust catalysts, drawn by slightly negative tailpipe pressure generated by the CVS during ICE shutdown may influence emission results.

Most of the recent clean diesel engines are equipped with an exhaust gas recirculation (EGR) technology in order to meet the strict criteria of NOx and particulate matter (PM) as required in the current emission regulations. More attention to strict EGR control is becoming required. Accurate and fast transient EGR ratio operation is becoming very critical in the field of the emission control. The EGR ratio is typically monitored by CO₂ trace method, in which CO₂ emitted from engine, is utilized as a tracer gas. The EGR ratio can be obtained from CO₂ concentration measured at engine intake and engine out at the same time. In this study, authors have developed a new EGR analyzer consisting of two CO₂ detectors, to achieve required performance for transient measurement, i.e., short delay time and quick response, negligible difference between two CO₂ detectors, and capability of wet measurement.

An analyzer based on Quantum Cascade Laser (QCL) has been developed for chemical sensing of gaseous nitrogen compounds (NO, NO2, N2O and NH3). The QCL can emit lights in a mid-infrared (Mid-IR) region where these nitrogen compounds have strong absorption. This laser optics configuration can give a super fine resolution of the mid-infrared spectrum. Therefore, utilizing this spectrometer can reduce the interference caused by the spectral overlap of co-existing gases in engine exhaust. The developed analyzer has been evaluated using actual engine exhaust to confirm the influence from coexisting gases and the measurement accuracies and stabilities. Very low detection limit (less than 1 ppm) and quick response time (less than 2 sec) have been achieved even with the newly developed analyzer.

An on-board diesel particulate measurement (OBS-TRPM) instrument is developed to measure on-road exhaust PM emission at Horiba. It is used to characterize particulate matter (PM) emission from a gasoline vehicle, the 1999 Ford Windstar with California Ultra Low Emission (ULEV) certification. PM emissions from three test cycles, EPA FTP 72, SFTP-US06, and new European drive cycle (NEDC), are evaluated. It is found that the PM emission from the SFTP-US06 with the cold start is roughly two times higher than PM emissions from the cold FTP 72 and the cold NEDC. This may be due to aggressive drive patterns for the US06 while the vehicle is still cold. The aggressive drive pattern for the US06 makes the gasoline vehicle emit a much higher fraction of elemental carbon (EC), and lower fraction of organic carbon (OC). Fractions of the EC from the vehicle are 9.1% for the FTP 72, 6.3% for the NEDC, and 56.6% for the US06.

The on-board transient response diesel particulate measurement (OBS-TRPM) instrument measures on-road vehicle particulate emissions. It is a continuation of the Horiba on-board PM sampler (OBS-PM) [5]. The OBS-TRPM measures total diesel particulate emission by collecting diesel particulate matter (PM) on a pre-weighed 47 mm filter while the partial flow sample system (OBS-PM) runs under a proportional control strategy. A real-time diffusion charge sensor (DCS) takes sample upstream of the filter, and measures diesel PM in term of particle length (mm/cm3). By integrating the DCS real-time signal during the filter sampling, the cumulative fraction of diesel PM emission is obtained. Finally, diesel PM mass emission during a specific region, for example a Not-to-Exceed (NTE) zone, is calculated from the fraction of the real-time PM signal. Thus, the OBS-TRPM provides a solution to measure PM emission in NTE zones which are defined by the US EPA.

The most serious problem in a 2-stroke spark-ignition engine is poor trapping of fresh charge. To solve this problem, a scavenging-port injection was applied, and a fuel injection pipe (FIP) was installed at the injector tip. In a previous study, it was shown that the BSFC and emission characteristics were drastically improved. In the present study, effect of increase in the fuel injection rate was investigated. It is shown that the BSFC and the THC emissions improved at high engine speeds, while they slightly deteriorate at low engine speeds. The increase in the fuel injection rate is effective particularly at high engine speeds, where the scavenging duration becomes shorter.

An analyzer for real-time measure of sulfur compounds in vehicle exhaust gas has been developed utilizing the Ultra Violet Fluorescence (UVF) detection technology. This analyzer measures Total Sulfur (TS) including sulfates in PM. For detecting sulfur components as TS, sample gas is introduced into two combustion furnaces. The TS measurement by the UVF analyzer is considered to be applicable to real-time oil consumption test with sulfur tracing method, because it has high sensitivity and quick response. In this study, the UVF method is evaluated in detail based on the vehicle emission test results.

A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.

Colloidal crystalline arrays are three dimensionally periodic lattices of self-assembled monodisperse colloidal spheres. We have demonstrated the synthesis of silica or polystyrene spheres uniformly coated with titania nanosheets and the fabrication of these spheres into close-packed colloidal crystalline arrays. The Bragg diffraction peak of the colloidal crystalline array shifted to longer wavelengths with increasing thickness of titania nanosheets layers. Angle-resolved reflection spectra measurements showed that this red shift was caused by increasing the mean effective refractive index neff of this crystalline lattice without changing interplanar spacing d111 with increasing thickness of titania nanosheets layers.

In response to the appearance of formal regulations, CFR part 1065 subpart J, a new in-use emission measurement system was developed, the OBS 2000. The OBS 2200 uses partial-vacuum analyzers. The heated flame ionization detector (HFID), heated chemiluminescence detector (HCLD) and heated non-dispersive infrared analyzer (HNDIR) are all upstream of the sample pump. This design decreases the response time of the analyzers, lowers power consumption and minimizes the overall dimensions of the system by avoiding the use of a heated sample pump. The size of the heated zones is also minimized to reduce power usage. Typical power consumption of analyzer unit is less than 500 W. The overall dimension of the main unit is 350mm (W) × 330mm (H) × 500mm (D). Analyzer linearity checks as required by new regulations [1] for all available ranges will be presented along with cut point accuracies relative to full scale and percentage of point.

The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.

A sulfur analyzer utilizing an ultraviolet fluorescent (UVF) detector has been developed to measure sulfur components in vehicle emissions. Generally, it is considered that an UVF detector cannot be used to measure sulfur components in vehicle emission due to a significant interference from NO in sample gases. In this study, an O3 injection technique has been developed to eliminate NO interference. Using this technique, the interference from NO has been reduced to less than 0.01 ppm with 3000 ppm NO. These result show a capability of utilizing UVF with this O3 injection technique to measure sulfur components in vehicle emissions including emissions with high concentrations of NO. An oxidation catalyst has also been evaluated to measure total reduced sulfur, TRS.

Continuous measurement of dilute exhaust gas from the CVS system, which provides gas concentrations proportional to the mass of emissions, is widely used for modal mass analysis of exhaust emission. Recently, exhaust gas flow rate measurement devices have become commercially available. Cost-effective raw exhaust modal mass analysis will be feasible with a combination of the new exhaust gas flow meters and fast response gas analyzers. In this paper, the benefits of raw exhaust modal mass measurement and the impacts of response time for the gas analyzer on the accuracy of exhaust mass calculations are discussed. Gas analyzer system with enhanced speed of response has been developed by hardware modification applied to the existing conventional bench system. De-convolution or inverse digital filter techniques that compensate the delay in the exhaust sampling system and the gas analyzer are described with comparisons to the hardware modifications.

Due to a need for a robust measurement system for on-board real-world vehicle emission measurement, a heated ND-IR(h-NDIR) technique has been developed and evaluated for its potential. The h-NDIR is capable of measuring CO and CO2 under wet-based condition by correcting interference from co-existing gas with an algorithm specially developed for the present study. The resulting H2O interference to the CO2 measurement is less than 0.01vol% for zero point and less than ±1% for span points and that of CO measurement is less than 0.001vol% for zero point and less than ±2% for span point against 0 to12vol% H2O. An on-board emission measurement system using the h-NDIR in combination with an Annubar® flow meter and an air to fuel ratio sensor has been evaluated. The result reveal correlation between the present system and a chassis test system to be within 7% for fuel consumption, within 5% for CO mass emission, and within 6% for CO2 mass emission.