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Honeycomb substrates are widely used to reduce harmful emissions from gasoline engines and are exposed to numerous thermal shocks during their lifetime making thermal shock resistance one of the key factors in designing honeycomb substrates. More stringent emission regulations will require the honeycomb substrates to be lighter in weight to improve light-off performance and to have better thermal shock resistance than conventional honeycomb substrates to handle higher expected temperature gradients. Thermal shock resistance is generally evaluated on a substrate by evaluating the thermal strain caused by temperature gradients inside the substrate during durability testing [1,2]. During the test, a heated substrate is cooled at a surface face to generate temperature gradients while the temperature inside the honeycomb substrate is monitored by multiple thermocouples.

Gasoline Direct Injection (GDI) engines achieve better fuel economy but have the drawback of increased Particulate Matter (PM) emissions. As known from diesel engine applications particulate filters are an effective PM reduction device which is expected to be effective for reduction of particulates emitted by GDI engines as well. For this investigation new filter concepts especially designed for GDI applications are proposed. Filtration efficiency, pressure drop and regeneration performance were verified by cold flow bench and engine and chassis dynamometer testing. The experimental data were used to discuss the validity of these new filter design concepts.

The Inlet-Membrane DPF which has a small pore size membrane formed on the inlet side of the body wall has been developed as a next generation diesel particulate filter (DPF). It simultaneously realizes low pressure drop, small pressure drop hysteresis, high robustness and high filtration efficiency. The low pressure drop improves fuel economy. The small pressure drop hysteresis has the potential to extend the regeneration interval since the linear relationship between the pressure drop and accumulated soot mass improves the accuracy of the soot mass detection by means of the pressure drop values. The Inlet-Membrane DPF's high robustness also extends the regeneration interval resulting in improved fuel economy and a lower risk of oil dilution while its high filtration efficiency reduces PM emissions. The concept of the Inlet-Membrane DPF was confirmed using disc type filters in 2008 and its performances was evaluated using full block samples in 2009.

Although diesel engines are superior to gasoline engines in terms of the demand to reduce CO2 emissions, diesel engines suffer from the problem of emitting Particulate Matter (PM). Therefore, a Diesel Particulate Filter (DPF) has to be fitted in the engine exhaust aftertreatment system. From the viewpoint of reducing CO2 emissions, there is a strong demand to reduce the exhaust system pressure drop and for DPF designs that are able to help reduce the pressure drop. A wall flow DPF having a novel wall pore structure design for reducing pressure drop, increasing robustness and increasing filtration efficiency is presented. The filter offers a linear relationship between PM loading and pressure drop, offering lower pressure drop and greater accuracy in estimating the accumulated PM amount from pressure drop. First, basic experiments were performed on small plate test samples having various pore structure designs.

A wall flow diesel particulate filter (DPF) having a novel wall pore structure design for reducing backpressure, increasing robustness, and increasing filtration efficiency is presented. The filter offers a linear relationship between soot loading and backpressure, offering greater accuracy in estimating the amount of soot loading from backpressure. Basic experiments were performed on small plate test pieces having various pore structure designs. Soot generated by a Cast-2F propane burner having a controlled size distribution was used. Cold flow test equipment that was carefully designed for flow distribution and soot/air mixing was used for precise measurement of backpressure during soot loading. The upstream and downstream PM numbers were counted by Scanning Mobility Particle Sizer (SMPS) to determine soot concentration in the gas flow and filtration efficiency of the test pieces. Microscope observations of the soot trapped in the wall were also carried out.

A practical ZrO2 NOx sensor using dual oxygen pumping cells has been introduced for the control of NOx emitted from a lean-burn gasoline engine and diesel engine.(1),(2). However, the measuring accuracy was not high enough to be useful for controlling or monitoring a low level of NOx concentration such as several tens ppm behind a three way catalyst or lean NOx catalyst which is NOx adsorption or De-NOx catalyst. This paper describes improvement of the interference effect of oxygen in the exhaust gas from the lean-burn gasoline engine and diesel engine. The cause of oxygen dependency is analyzed/revealed and a method of improvement is introduced. The improved NOx sensor has an approximately · · 2% measuring error in the wide range of oxygen concentration on a model gas system, compared to the · ·10% of the previous one.

This paper describes a thick film ZrO2 NOx sensor feasible for diesel and gasoline engine applications, and introduces modification items from the previous concept design.(1) The modification items comprise simplifying the sensing element design to reduce output terminals for package design and applying temperature control to the sensing element in order to minimize sensor performance dependency on gas temperature. The NOx sensor indicates a stable linear signal in proportion to NOx concentration in a wide range of temperature, A/F and NOx concentration as a practical condition on both gasoline and diesel engines. The NOx sensor shows a good response in hundred msec. and a sharp signal following NOx generation in a transient state as well. Besides, another type of a NOx sensor is proposed for low NOx measurement in a practical use, by an electromotive force(EMF) voltage instead of a pumping current.

This paper proposes a high temperature catalytic converter design using a ceramic substrate and intumescent matting. It also describes the improvement of converter performance using an advanced thin wall ceramic substrate. Due to future tightening of emission regulations and improvement of fuel economy, higher exhaust gas temperatures are suggested. Therefore, reduction of thermal reliability of an intumescent mat will be a concern because the catalytic converter will be exposed to high temperatures. For this reason, a new design converter has been developed using a dual cone structure for both the inlet and outlet cones. This minimizes heat conduction through the cone and decreases the temperature affecting the mat area. This design converter, without the use of a heat-shield, reduces the converter surface temperature to 441°C despite a catalyst bed temperature of 1050°C. The long term durability of the converter is demonstrated by the hot vibration test.

This paper describes the design and operation of the multi-layered zirconia heated exhaust gas oxygen sensor having small-sized and sheet-shaped sensing element. This sensor uses an electrode modified with a rhodium catalyst and heater by means of the thick-film technique. This modification of an electrode's composition and construction affects the reaction on unburned components in exhaust gas as well as the sensor performance. By the addition of a rhodium catalyst, the zirconia exhaust gas oxygen sensor shows acute sensitivity and faster response properties in the transient state on emission component(NOx) generation, in such a way that these sensors show better emission control properties for reduction of NOx emission in current emission control systems. The addition of a rhodium catalyst reduces the green effect of sensor properties, and no significant change of emission control properties is observed after 50,000 equivalent miles using the engine dynamometer durability test.